题目：Heterojunction Perovskite Solar Cells: Opto-Electro-Thermal Physics, Modeling, and Experiment

作者：Yidan An,^a,b,#Changlei Wang,^a,b,#Guoyang Cao^cand Xiaofeng Li^a,b,*

单位：

^aSchool of Optoelectronic Science and Engineering & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215006, China;

^bKey Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province & Key Lab of Modern Optical Technologies of Education Ministry of China, Soochow University, Suzhou 215006, China;

^cSchool of Science, Jiangsu Provincial Research Center of Light Industrial Optoelectronic Engineering and Technology, Jiangnan University, Wuxi 214122, China;

摘要：Organic−inorganic heterojunction perovskite solar cell (PSC) is promising for low-cost and high-performance photovoltaics. To further promote the performance of PSCs, understanding and controlling the underneath photoconversion mechanisms are highly necessary. Here, we present a comprehensive opto-electro-thermal (OET) study on the heterojunction PSCs by quantitatively addressing the coupled optical, carrier transport, and thermodynamic behaviors within the device. With achieving a good agreement with the experiment, we theoretically explore the thermodynamic mechanisms involving the energy conversions and focus especially on the origins of the various energy losses in PSCs. We summarize six categories of microscopic heat conversion processes in the heterojunction PSC, where the Joule and Peltier heats can be defined as the intrinsic losses in PSCs. Moreover, we also discuss the possible manipulation methods to decrease the energy losses, for example, by tailoring the doping concentration and energy-level alignment. An exemplified OET optimization is also presented, which predicts that the PCE of the fabricated PSC can be enhanced from 21.37% to 23.84%.

影响因子：13.903

分区情况：一区

链接：https://pubs.acs.org/doi/10.1021/acsnano.0c01392