YANG, Biao

Professor

Email:yangbiao@suda.edu.cn

Academic experience:

Research Experience and Accomplishments:

Prof. Yang focuses on the subjects of physical properties and catalytic chemical reactions on material surfaces. Using spatially resolved scanning probe microscopy and chemically resolved photoelectron spectroscopy as the main tools, he has systematically investigated the on-surface chemical reactions in the single molecular level, based on the prototypes system of organic molecules with specific functional groups adsorbed on the single crystal surfaces. 1) Pioneering research on the C-H bond activation on metal surfaces; surface controlled mono-/di-selective C-H bond activation; intermediate-directed chiral transfer from assembly to reaction. 2) Development of surface two-component condensation reaction. 3) Expand the substrates for on-surface chemical reactions: the surface preparation and physical properties of narrow-bandgap semiconductors.

Prof. Yang has published more than 20 journal papers, of which 13 papers have been published in world-class journals as the first author or corresponding author. Recipient of TUM University Foundation Fellowship and Humboldt Foundation Postdoctoral Fellowship. He intends to build a combined characterization system based on scanning probe microscopy and X-ray photoelectron spectroscopy, conduct research of on-surface chemical reactions methodology based on complex monomer molecules with dual (multi) functional groups, to develop surface synthesis methods for precise construction of new functional nanomaterials.

Selected Publications:(# co-first author, *co-corresponding author)

1. Biao Yang+*, Kaifeng Niu+, Nan Cao, Nitika Grover, Wenchao Zhao, Alexander Riss, Jonas Björk*, Willi Auwärter, Johannes V. Barth*, and Mathias O. Senge*. “On-Surface Synthesis of Polyphenylene Wires Comprising Rigid Aliphatic Bicyclo[1.1.1]Pentane Isolator Units”,Angew. Chem. Int. Ed.e202218211 (2023)

2. Nan Cao+,Biao Yang+(co-first)*, Alexander Riss, Johanna Rosen, Jonas Björk*, and Johannes V. Barth. “On-Surface Synthesis of enetriynes”,Nat. Commun.14, 1255 (2023)

3. Luying Song+,Biao Yang+(co-first),Xing Fan, Yahui Mao, Huan Shan, Junbo Wang, Kaifeng Niu, Zhengming Hao, Zhiwen Zeng, Youyong Li, Aidi Zhao*, Haiping Lin*, Lifeng Chi*, and Qing Li*.“Intra- and Inter-Self-Assembly of Identical Supramolecules on Silver Surfaces”J. Phys. Chem. L13, 8902-8907(2022).

4. Biao Yang+*, Kaifeng Niu+, Felix Haag, Nan Cao, Junjie Zhang, Haiming Zhang, Qing Li, Francesco Allegretti, Jonas Björk, Johannes V. Barth*, and Lifeng Chi*. “Abiotic Formation of an Amide Bond via Surface-Supported Direct Carboxyl-Amine Coupling”,Angew.Chem. Int. Ed.e202113590 (2021)

5. Biao Yang+, Martin Uphoff+, Yi-Qi Zhang+*, Joachim Reichert, Ari Paavo Seitsonen, Andreas Bauer, Christian Pfleiderer, and Johannes V. Barth*.“Atomistic investigation of surface characteristics and electronic features at high-purity FeSi(110) presenting interfacial metallicity”PNAS118, e2021203118 (2021)

6. Biao Yang, Bin Dong, and Lifeng Chi*.“On-Surface Intramolecular Reactions”ACS Nano14, 6376-6382 (2020). (Perspectives)

7. Luying Song+,Biao Yang+(co-first),Fangfang Liu, Kaifeng Niu, Yangyang Han, Junbo Wang, Yuanjing Zheng, Haiming Zhang, Qing Li*, and Lifeng Chi*.“Synthesis of Two-Dimensional Metal–Organic Frameworks via Dehydrogenation Reactions on a Cu(111) Surface”J. Phys. Chem. C124, 12390-12396(2020).

8. Biao Yang, Nan Cao, Huanxin Ju, Haiping Lin*, Youyong Li, Honghe Ding, Jinqiang Ding, Junjie Zhang, Chencheng Peng, Haiming Zhang, Junfa Zhu, Qing Li*andLifeng Chi*.“Intermediate States Directed Chiral Transfer on a Silver Surface”J. Am. Chem. Soc.141, 168-174 (2019).

9. Qing Li+,Biao Yang+(co-first),Jonas Björk, Qigang Zhong, Huanxin Ju, Junjie Zhang, Nan Cao, ZiliangShi, Haiming Zhang, Daniel Ebeling, Andre Schirmeisen, Junfa ZhuandLifeng Chi*. “Hierarchical Dehydrogenation Reactions on a Copper Surface”J. Am. Chem. Soc.140, 6076-6082 (2018). (Cover)

10. Biao Yang+, Haiping Lin+, Kangjian Miao, Pan Zhu, Liangbo Liang, Kewei Sun, Haiming Zhang, Jian Fan, Vincent Meunier, Youyong Li, Qing Li* and Lifeng Chi*. “Catalytic Dealkylation of Ethers to Alcohols on Metal Surfaces”Angew. Chem. Int. Ed.55, 9881-9885 (2016).

11. Qing Li+,Biao Yang+(co-first), Haiping Lin+, Nabi Aghdassi, Kangjian Miao, Junjie Zhang, Haiming Zhang, Youyong Li, Steffen Duhm, Jian Fan* and Lifeng Chi*. “Surface-Controlled Mono/Diselective ortho C−H Bond Activation”J. Am. Chem. Soc.138, 2809-2814 (2016).

12. Zhongmiao Gong+,Biao Yang+(co-first), Haiping Lin, Yunyu Tang, Zeyuan Tang, Junjie Zhang, Haiming Zhang, Youyong Li, Yongshu Xie, Qing Li* and Lifeng Chi*.“Structural Variation in Surface-Supported Synthesis by Adjusting the Stoichiometric Ratio of the Reactants”ACS Nano10, 4228-4235 (2016).

13. Biao Yang, Jonas Björk, Haiping Lin, Xiaoqing Zhang, Haiming Zhang, Youyong Li, Jian Fan, Qing Li* and Lifeng Chi*. “Synthesis of Surface Covalent Organic Frameworks via Dimerization and Cyclotrimerization of Acetyls”J. Am. Chem. Soc.137, 4904-4907 (2015).

Edited by Juan Yang