Name:XU Fan Title:Professor Contacts:
Tel: 86-512-65880331 (o), 65880980 (Lab)
Fax: 86-512-65880305 (o)
Email:
xufan@suda.edu.cn
Group Website |
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Research Interests:design, synthesis and applications of lanthanide compounds as catalysts; development of selective methods for the organic synthesis.
Representative Publications
1.
Samarium Diiodide Promoted Synthesis ofN,N’-Disubstituted Amidines,F. Xu, J. Sun, Q. Shen,Tetrahedron Lett.2002,43, 1867.
2
.
One-pot Synthesis of α-Amino Phospho- nates Using Samarium Diiodide as a Catalyst Precursor,F. Xu, Y. Luo, Q. Shen,Eur. J. Org. Chem.2003,24, 4728.
3.
Efficient Synthesis of 1,5-Benzodiazepine Derivatives by Ytterbium Trichloride-Catalyzed Condensation ofo-Phenylenediamine and Ketones, J. Wu,F. Xu*, Z. Zhou, Q. Shen,Synth. Commun.2006,36, 457.
4.
Facile One-pot Synthesis of α-AminoPhosphonatesUsing Lanthanide Chloride as Catalyst,F. Xu, Y. Luo, J. Wu, Q. Shen, H. Chen,Heteroatom Chem.2006,17, 389.
5.
Stereoselective Synthesis of Pyrano[3,2-c]- and Furano[3,2-c]Quinolines:
Samarium Diiodide Catalyzed One-Pot Aza
–
Diels
–
Alder Reaction,Z. Zhou,
F. Xu
*
,X. Han
,
J. Zhou,
Q. Shen,
Eur. J. Org. Chem.
2007
,
5265.
6.
Efficient Synthesis of Pyrimidinone Derivatives by Ytterbium Chloride Catalyzed Biginelli-type Reaction under Solvent-free Conditions,H. Zhang, Z. Zhou, Z. Yao,F. Xu
*
,
Q. Shen,
Tetrahedron Lett.
2009
,50, 1622.
7.
AFacileRouteto1,5-Benzodiazepine-2-ylphosphonatesvia Ytterbium Chloride-Catalyzed Three-Component Reaction,X. Ji, L. Cai, Z. Yao,F. Xu*, Q. Shen,Heteroatom Chem.
2010
,21, 89.
8.
StereoselectiveSynthesis of Pyrano[3,2-c]- and Furano[3,2-c]quinolines: Gadolinium Chloride Catalyzed One-pot Aza
-
Diels
-
Alder Reactions, Y. Yu, J. Zhou, Z. Yao,
F. Xu
*
, Q. Shen,Heteroatom Chem.
2010
,21, 351.
9.
Lanthanide Amides[(Me3Si)2N]3Ln(
m
-Cl)Li(THF)3
Catalyzed
Hydrophosphonylation of Aryl Aldehydes,Q. Wu, J. Zhou, Z. Yao,F. Xu
*
, Q. Shen,
J. Org. Chem.
2010
,75, 7498.
10.
Controllable Stereoselective Synthesis of Pyrano[3,2-c]quinolines by Lanthanide Halides Catalyzed Aza-Diels-Alder Reaction, L. Yao,F. Xu*, Q. Shen,Chinese Science Bulletin
2010
,55, 4108.
11.
Acylation of Nitriles to β-Ketonitriles Catalyzed by Heterometal Alkoxide Cluster of Neodymium and Sodium NdNa8(OtBu)10(OH),H. Liu,L. Li, H. Sheng, X. Zhu,F. Xu
*
, Q. Shen,Chinese Science Bulletin,2011,56, 1357.
12.Activation of Carbodiimide and Transformation with Amine to Guanidinate Group by Ln(OAr)3(THF)2(Ln: Lanthanide and Yttrium) and Ln(OAr)3(THF)2as a Novel Precatalyst for Addition of Amines to Carbodiimides: Influence of Aryloxide Group, Y. Cao, Z. Du, W. Li, J. Li, Y. Zhang,F. Xu*, Q. Shen*,Inorganic Chemistry2011,50, 3729.
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