Precise Modulation of Circularly Polarized Luminescence via Polymer Chiral Co-assembly and Contactless Dynamic Chiral Communication
Gong Zhang1*（张弓）, Yinglong Bao1, Haotian Ma1, Nianwei Wang1,Xiaoxiao Cheng1, Zixiang He1, Xiang Wang1,Tengfei Miao3, Wei Zhang1,2*（张伟）
1Stateand LocalJoint EngineeringLaboratoryfor NovelFunctionalPolymericMaterials,JiangsuEngineeringLaboratoryof NovelFunctionalPolymericMaterials,SuzhouKey Laboratoryof Macro-molecularDesignand PrecisionSynthesis,Collegeof Chemistry,ChemicalEngineeringand MaterialsScience,SoochowUniversity,Suzhou,215123(China)
2DepartmentSchoolof Chemicaland EnvironmentalEngineeringAnhuiPolytechnicUniversityWuhu, 241000(China)
3JiangsuKey Laboratoryfor Chemistryof Low-DimensionalMaterials, Schoolof Chemistryand ChemicalEngineeringHuaiyinNormalUniversityHuaian,223300(China)
Angew. Chem.Int. Ed.2024,63,e202401077(1 of 11）
Abstract:Circularly polarized luminescence (CPL) plays a pivotal role in cutting-edge display and information technologies. Currently achieving precise color control and dynamic signal regulation in CPL still remains challenging due to the elusory relationship between fluorescence and chirality. Inspired by the natural mechanisms governing color formation and chiral interaction, we proposed an addition-subtraction principle theory to address this issue. Three fluorene-based polymers synthesized by Suzuki polycondensation with different electron-deficient monomers exhibit similar structures and UV/Vis absorption, but distinct fluorescence emissions due to intramolecular charge transfer. Based on this, precise-color CPL-active films are obtained through quantitative supramolecular co-assembly directed by addition principle. Particularly, an ideal white-emitting CPL film (CIE coordinates: (0.33, 0.33)) is facilely fabricated with a high quantum yield of 80.8 % and a dissymmetry factor (glum) of 1.4x10-2. Structural analysis reveals that the ordered stacking orientation favors higher glum. Furthermore, to address the dynamically regulated challenge, the comparable subtraction principle is proposed, involving a contactless chiral communication between excited and ground states. The representative system consisting of as-prepared fluorene-based polymers and chirality-selective absorption azobenzene (Azo)-containing polymers is constructed, achieving CPL weakening, reversal, and enhancement. Finally, a switchable quick response code is realized based on trans-cis isomerization of Azo moiety.
链接：https://onlinelibrary.wiley.com/doi/10.1002/anie.202401077
