A lanthanide–titanium (LnTi₁₁) oxo-cluster, a potential molecule based fluorescent labelling agent and photocatalyst

Guang-Lin Zhang,^aSheng Wang,^aJin-Le Hou,^aChong-Jiao Mo,^aChen-Jie Que,^aQin-Yu Zhu*^a（朱琴玉）andJie Dai*^a（戴洁）

^aCollege of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, People's Republic of China

Dalton Trans.,2016,45, 17681-17686

Although a lot of titanium oxo-clusters (TOCs) have been synthesized and characterized, research studies on their application properties are still limited. The work described here is not only aimed at the synthesis and crystal structures of the TOCs, but also aimed at exploration of their potential applications in molecule based fluorescence labelling and photocatalysis. Three heterometallic TOC compounds with lanthanide (Ln) elements Sm(III) (1), Eu(III) (2) and Gd(III) (3) are prepared and their cluster structures are characterized as LnTi₁₁cages. Compound2exhibits the characteristic fluorescence of Eu(III) and the emission intensity can be decreased upon irradiation and recovered by air oxidation, which is attributed to the energy transfer between Eu(III) and photo-induced Ti(III) of the oxo-TiO cluster. The fluorescence intensity of2can be significantly increased when treated with 1,10-phenanthroline. The catalytic properties of2were determined by the degradation of dyes on a paper substrate. Compound2has potential applications as a molecule based fluorescent labelling agent and photodegeneration catalyst.

链接：http://pubs.rsc.org/en/Content/ArticleLanding/2016/DT/C6DT03034C#!divAbstract