姓名:徐小平 职称:研究员 www.优德88.cpm 有机合成省级重点实验室秘书 部门:化学学院联系方式:
电话:0512-65883304
Email:xuxp@suda.edu.cn 课题组网站 |
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1997.9-2001.6南京师范大学化学院学士 2001.9-2004.6www.优德88.cpm 化学化工学院硕士 2004.8-2007.6www.优德88.cpm 化学化工学院博士 2007.8-至今www.优德88.cpm 材料与化学化工学部教师 www.优德88.cpm 有机合成省级重点实验室秘书
学术经历:主持国家自然科学基金面上项目一项,完成国家基金委青年基金一项,作为第二参与人完成国家基金面上项目两项,完成江苏省省属高校自然科学基础研究项目、江苏省有机合成重点实验室开放课题各一项。以通讯作者的身份在国内外核心化学期刊如Chem. Commun.,Org. Lett.,Adv. Synth. Catal., Chem. Eur. J., ACS Appl. Mater. Interfaces等发表论文六十余篇,参与的项目获得了包括教育部自然科学二等奖、江苏省科学技术进步奖二等奖、中国石油与化学工业联合会科技进步二等奖在内的部、省、市级奖项六项。 教学经历:担任本科生《有机化学》,《有机化学实验》,《化学与健康》等课程的教学任务。 研究领域 : 催化剂导向及介质调控的高效及高选择性反应;有机功能分子的构筑及应用基础。代表性论文及参编著作:
1.Treatment of Olefinic Amides with NBS in Water: Synthesis ofMonobromo- and Multibromobenzoxazines, Xu Zhang, Wen-Bin Cao,Xiao-Ping Xu*, Shun-Jun Ji*,Synthesis2019,51,DOI: 10.1055/s-0037-1610724.
2.Dearomatization of Indoles via Azido Radical Addition andDioxygen Trapping To Access 2‑Azidoindolin-3-ols, Meng-Meng Xu, Wen-Bin Cao, Rao Ding, Hai-Yan Li,Xiao-Ping Xu*, Shun-Jun Ji*,Org. Lett.2019,21, 6217.
3.Cooperation ofMn(III)/Brønsted Acid for the Synthesis of Quindoline DerivativesviaDehydroxylation/Azidation/Cyclization Cascade of Diaryl(1H-indol-2-yl)methanols with Trimethylsilyl Azide,Yu Zhou,Xiao-Ping Xu*, Shun-Jun Ji*,Org. Lett.2019,21,2039.
4.Visible-light-induced oxidative ring expansion of indoles with amidines, Ling-Ling Zhang, Wen-Bin Cao,Xiao-Ping Xu*, Shun-Jun Ji*,Org. Chem. Front.2019, 6,1787.
5.Copper‐Catalyzed Sequential C(sp2)/C(sp3)−H Amination of 2‐Vinylanilines with N‐Fluorobenzenesulfonimide,Wen-Bin Cao,Xiao-Ping Xu*, Shun-Jun Ji*,Adv. Synth, Catal.2019,361, 1771.
6.Efficient synthesis of 2-arylquinazolin-4-amines via a copper-catalyzed diazidation and ring expansion cascade of 2-arylindoles,Meng-Meng Xu, Wen-Bin Cao,Xiao-Ping Xu*, Shun-Jun Ji*,Chem. Commun.2018,54, 12602.
7.Ag(I)-Promoted Dehydroxylation and Site-Selective 1,7-Disulfonylation of Diaryl(1H‑indol-2-yl)methanols, Yu Zhou, Wen-Bin Cao, Ling-Ling Zhang,Xiao-Ping Xu*, Shun-Jun Ji*,J. Org. Chem.2018,83, 6056.
8.Cooperation of Copper and Dioxygen for the Site-selective Construction of Benzo[1,5]diazocin-6(5H)-ones from Indoles and Enaminone Analogues, Wen-Bin Cao, Bei-Bei Liu,Xiao-Ping Xu*, Shun-Jun Ji*,Org. Chem. Front.2018, 5, 1194.
9.Inkjet-Printed Quantum Dot Light-Emitting Diodes with an Air-Stable Hole Transport Material, Zhenhua Xing, Jinyong Zhuang*, Changting Wei, Dongyu Zhang, Zhongzhi Xie,Xiao-ping Xu*, Shunjun Ji, Jianxin Tang, Wenming Su*, and Zheng Cui,ACS Appl. Mater. Interfaces2017,9, 16351.
10.Iron Catalysis for Modular Pyrimidine Synthesis throughβ-Ammoniation/Cyclization of Saturated Carbonyl Compounds with Amidines, Xue-Qiang Chu, Wen-Bin Cao,Xiao-Ping Xu*, Shun-Jun Ji*,J. Org. Chem.2017,82, 1145. 11.Copper-catalyzed construction of eight-membered rings via oxidative ring expansion and intermolecular cyclization sequencing of indoles with amidines: efficient synthesis of benzo[1,3,5]triazocin-6(5H)-ones, Wen-Bin Cao, Xue-Qiang Chu, Yu Zhou, Ling Yin,Xiao-Ping Xu*, Shun-Jun Ji*,Chem. Commun.2017,53, 6601. 12.Palladium-Catalyzed Cyclization of Alkenes with Organohalides, Xue-Qiang Chu, Dan Liu, Zhen-Hua Xing,Xiao-Ping Xu*, Shun-Jun Ji*,Org. Lett.2016,18, 776.
13.Copper-mediated radical alkylarylation of unactivated alkenes with acetonitrile leading to fluorenes and pyrroloindoles, Xue-Qiang Chu, Zhen-Hua Xing, Hua Meng,Xiao-Ping Xu*, Shun-Jun Ji*,Org. Chem. Front.2016,3, 165.
14.TBAI-Catalyzed/Water-Assisted Double C-S Bond Formations: An Efficient Approach to Sulfides through Metal-Free Three-Component Reactions, Xue-Qiang Chu,Xiao-Ping Xu*,Shun-Jun Ji*,Chem. Eur. J.2016,22, 14181.
15.One-Pot Synthesis of Allylic Sulfones, Ketosulfones, and Triflyl Allylic Alcohols from Domino Reactions of Allylic Alcohols with Sulfinic Acid under Metal-Free Conditions, Xue-Qiang Chu, Hua Meng,Xiao-Ping Xu*, Shun-Jun Ji*,Chem. Eur. J.2015,21, 11359. 16.Oxidative C(sp3)–H functionalization of acetonitrile and alkanes with allylic alcohols under metal-free conditions, Xue-Qiang Chu, Hua Meng, You Zi,Xiao-Ping Xu*, Shun-Jun Ji*,Org. Chem. Front.2015,2, 216.
17.Metal-Free Oxidative Radical Addition of Carbonyl Compounds toα,α-Diaryl Allylic Alcohols: Synthesis of Highly Functionalized Ketones, Xue-Qiang Chu, Hua Meng, You Zi,Xiao-Ping Xu*, Shun-Jun Ji*,Chem. Eur. J.2014,20, 17198.
18.Metal-free oxidative direct C(sp3)–H bond functionalization of ethers withα,α-diaryl allylic alcohols, Xue-Qiang Chu, Hua Meng, You Zi,Xiao-Ping Xu*, Shun-Jun Ji*,Chem. Commun.2014,50, 9718. 19. Radical phosphinylation of α,α -diaryl allylic alcohols with concomitant 1,2-aryl migration, Xue-Qiang Chu, You Zi, Hua Meng,Xiao-Ping Xu*, Shun-Jun Ji*,Chem. Commun.2014,50, 7642.
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