郎建平教授在Chem. Commun.发表研究论文

Stepwise ligand transformations through [2+2] photodimerization and hydrothermalin situoxidation reactions

Dong Liu,abJian-Ping Lang*a(郎建平)andBrendan F. Abrahamsc

aCollege of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 RenAi Road, Suzhou 215123, P. R. China

bCollege of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, P. R. China

cSchool of Chemistry, University of Melbourne, Australia

Chem. Commun.2013,49, 2682-2684.

The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)2]nproduced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)0.5]nthrough the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H2bdc and H2O2afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]·H2O}nin which HT-ppcb underwentin situoxidation to form a unique furan-based ligand bpbpf.



链接:http://pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc39286d#!divAbstract