Thermally Conductive Aluminum Nitride–Multiwalled Carbon Nanotube/Cyanate Ester Composites with High Flame Retardancy and Low Dielectric Loss

Ya-nan Mi,Guozheng Liang*（梁国正）,Aijuan Gu*（顾嫒娟）,Feipeng Zhao, andLi Yuan

Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Materials Science and Engineering,

College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, Jiangsu 215123, China

Ind. Eng. Chem. Res.2013,52, 3342–3353.

New high-performance composites with high thermal conductivity, good flame retardancy, and low dielectric loss using cyanate ester (CE) resin as the matrix and hybrid fillers consisting of aluminum nitride (AlN) and multiwalled carbon nanotubes (MCNTs) as the functional phase were developed. In addition to the original fillers, surface-treated AlN (kAlN) and MCNTs (eMCNTs) were prepared to develop four types of hybrid fillers and the corresponding composites. The structures and properties of the ternary composites can be adjusted by controlling the interaction between the nanotubes and the AlN. Both AlN and kAlN fillers can improve the dispersion of nanotubes in the CE resin, regardless of whether the nanotubes are modified, whereas only eMNCTs can improve the dispersion of AlN or kAlN in the matrix. The kAlN–eMCNT hybrid was found to have the highest synergistic effect, endowing CE resin with outstanding thermal conductivity, low dielectric loss, significantly improved processing characteristics, and flame retardancy.

链接：http://pubs.acs.org/doi/abs/10.1021/ie3029569