学历及学术经历：张正彪，1997年、2000年和2007年在www.优德88.cpm 化学化工学院（现材料与化学化工学部）分别获化学工程学士学位、高分子化学与物理硕士和博士学位。2000年硕士毕业后留校任助教，历任讲师（2003）、副教授（2009）、教授（2013）和特聘教授（2018）。2007 -2008年新加坡国立大学博士后；2012-2013年美国阿克伦大学访问学者；2015年日本名古屋大学访问教授。现任材化部党委委员、学部学术分委员会委员及校研究生教育督查与指导委员会成员等职。张正彪教授自工作以来，针对高分子合成化学领域的前沿和挑战性的科学问题，系统地开展了高分子精准合成基础研究。近年来，在Nat. Commun.，Angew. Chem. Int. Ed.，Macromolecules，Polym. Chem.等刊物发表研究论文160余篇；获中国发明专利授权22项。获日本化学会Distinguished Lectureship Award；任环太平洋化学大会（PACIFICHEM 2020）分会负责人；主办2届国际高分子精准合成研讨会，并担任会议主席。受邀在第99届日本化学年会作Keynote Lecture、全国高分子学术论文报告会（2015、2017和2019）、环太平洋化学大会（PACIFICHEM 2015）、国际高分子化学研讨会（Warwick2016）、第255届美国化学会年会（2018）、有机和高分子合成国际会议（2018）等多个重要学术会议作邀请报告。受邀为期刊Polym. Chem.和Chin. J. Polym. Sci.撰写综述。受《高分子学报》邀请撰写特约专论；应邀担任《Giant》、《European Polymer Journal》、《Reactive Functional polymers》和《功能高分子学报》等杂志执行编委和顾问编委。被Polym. Chem.杂志遴选为Emerging Investigator。主持包括国家杰出青年科学基金等国家级项目多项和省高校重大自然www.优德88.cpm 计划1项。

研究领域：高分子精准合成、精密高分子结构与性能（功能）研究、数字高分子、可再生/仿生功能高分子、响应性功能高分子的设计和定制合成

欢迎报考化学或材料科学与工程方向研究生：

（一）化学；专业课：（1）无机化学或有机化学A（二选一）（2）分析化学、物理化学或高分子化学（三选一）；

（二）材料科学与工程；专业课：材料科学基础（无机非方向）、高分子物理、高分子材料化学三选一（高分子材料方向）。

获奖情况：

1. 日本化学会Distinguished Lectureship Award，2019；

2. 江苏省高校“青蓝工程”优秀青年骨干教师培养对象，2014；

3. 教育部自然科学二等奖，排五，2010；

4. 江苏省自然科学进步二等奖，排五，2010；

5. www.优德88.cpm 优秀博士论文，2008；

6. www.优德88.cpm 苏鑫科研奖，2008；

7. 指导国家级大学生创新性实验计划（2010）和校级大学生创新性计划（2009）各1项，结题均为优秀。

8. 主讲《化工原理》课程获www.优德88.cpm 精品课程。

主持项目：

1.国家杰出青年科学基金：高分子精准合成（21925107），400万元，2020.1–2024.12，主持。

2. 国家自然科学基金面上项目：基于可逆Diels-Alder反应构建复杂拓扑链结构以及分子量/序列明确的聚合物（21674072），直接费用68万元，2017.1-2020.12，主持。

3. 国家自然科学基金面上项目：基于非共价键相互作用和可控自由基聚合的大分子精密合成（21374068），83万元。2014.1-2017.12，主持。

4. 国家自然科学基金面上项目：室温下零价铁调控的“活性”/可控自由基聚合（21174094），62万元。2012.1-2015.12，主持。

5. 国家自然科学基金青年基金项目：单电子转移“活性”自由基聚合(SET-LRP)的机理研究（20904036），19万元，2010.1-2012.12，主持。

6. 江苏省高校自然www.优德88.cpm 重大项目：基于“活性”自由基聚合和分子间弱相互作用的大分子精密合成（12KJA150007），30万元，2012.8-2015.12，主持。

代表性论文：

1. Fufu Han, Qiunan Shi, Liuqiao Zhang, Baolei Liu, Yajie Zhang, Yang Gao, Rui Jia,Zhengbiao Zhang*and Xiulin Zhu. Stereoisomeric furan/maleimide adducts as latent monomers for one-shot sequence-controlled polymerization.Polym. Chem.,2020, accepted. 10.1039/C9PY01379B.

2. Baolei Liu, Qiunan Shi, Lihua Hu, Zhihao Huang, Xiulin Zhu andZhengbiao Zhang*. Engineering Digital Polymer Based on Thiol-Maleimide Michael Coupling Toward Effective Writing and Reading.Polym. Chem., 2020, accepted. 10.1039/C9PY01939A.

3. Yuqing Wang, Jiawei Yu, Zhe Wang, Shahid Iqbal, Wei Zhang,Zhengbiao Zhang*, Nianchen Zhou* and Xiulin Zhu. Real-time Near-infrared Fluorescent Reporting the Azoreductasetriggered Drug Release.Polym. Chem.,2020,11, 734–743.

4. Xiaojie Yuan, Zhe Wang, Lishan Li, Jiawei Yu, Yuqing Wang, Hongkun Li, Jiandong Zhang,Zhengbiao Zhang*, Nianchen Zhou* andXiulin Zhu. Novel fluorescent amphiphilic copolymer probes containing azo-tetraphenylethylene bridges for azoreductase-triggered release.Materials Chemistry Frontiers2019,3, 1097–1104.

5. Zhengbiao Zhang*, Baolei Liu, Zhihao Huang, Yufang Zhong, Qiunan Shi and Xiulin Zhu. Thiol Chemistry for Precision Polymer Synthesis. Synthetic Polymer Chemistry: Innovations and Outlook (Book). Chapter 2. 2019. 978-1-78801-523-3 (RSC).

6. Qiunan Shi, Yajie Zhang, Zhihao Huang*, Nianchen Zhou,Zhengbiao Zhang*and Xiulin Zhu. Precise sequence regulation through maleimide chemistry.Polymer Journal.2019, doi:10.1038/s41428-019-0263-7. (Focus Review).

7. Zhihao Huang, Qiunan Shi, Jiang Guo, Fanying Meng, Yajie Zhang, Yutong Lu, Zhuangfei Qian, Xiaopeng Li, Nianchen Zhou,Zhengbiao Zhang*& Xiulin Zhu. Binary tree-inspired digital dendrimer.Nature Communications2019,10:1918.

8. Jiawei Yu, Kun Li, Lishan Li, Lei Liu, Yechun Zhou,Zhengbiao Zhang*, Mingyu Guo*, Nianchen Zhou* and Xiulin Zhu. Photo-responsive gels based on cyclic/linearpolymers: efficient synthesis and properties.Polym. Chem.,2019,10, 2872–2880

9. Yanyan Zhou,Zhengbiao Zhang*, Almar Postma and Graeme Moad*. Kinetics and mechanism for thermal and photochemical decomposition of 4,4’-azobis(4-cyanopentanoic acid) in aqueous media.Polym. Chem.,2019,10, 3284–3287.

10. Liuqiao Zhang, Yuxuan Ji, Xue Gu, Wei Zhang, Nianchen Zhou,Zhengbiao Zhang*, Xiulin Zhu. Synthesis of sequence-controlled polymers with pendent “clickable” or hydrophilic groups via latent monomer strategy.Reactive and Functional Polymers.2019,138, 96–103.

11. Fanying Meng, Yajie Zhang, Kunshan Ding, Baolei Liu, Fufu Han, Yiying He, Nianchen Zhou,Zhengbiao Zhang*, Xiulin Zhu. One-shot synthesis of sequence-controlled polymers with versatile succimide motifs for post-modifications.Reactive and Functional Polymers2019,134, 67–73.

12. Qilong Li，Jiandong Zhang，Xiangqiang Pan*，Zhengbiao Zhang*，Jian Zhu*，Xiulin Zhu. Selenide-Containing Polyimides with an Ultrahigh Intrinsic Refractive Index.Polymers2018,10, 417.

13. Yanyan Zhou, Lei Li, Wei Chen, Dian Li, Nianchen Zhou, Jinlin He,* Peihong Ni,Zhengbiao Zhang*and Xiulin Zhu. A twin-tailed tadpole-shaped amphiphilic copolymer of poly(ethylene glycol) and cyclic poly(ε-caprolactone): synthesis, self-assembly and biomedical applications.Polym. Chem.2018,9, 4343–4354.

14. Liuqiao Zhang, Zhihao Huang,Zhengbiao Zhang*, Xiulin Zhu. Synthesis and Application of Sequence-controlled Polymers.Acta Polymerica Sinica.2018,9, 1144–1154.

15. Lishan Li, Feng Zhou, Yiwen Li, Xiaofang Chen,Zhengbiao Zhang*, Nianchen Zhou,*and Xiulin Zhu.Langmuir2018,34, 11034–11041.

16. Yu Zhou, Yangcui Qu, Qian Yu, Hong Chen,Zhengbiao Zhang*and Xiulin Zhu. Controlled synthesis of diverse single-chain polymeric nanoparticles using polymers bearing furan-protected maleimide moieties.Polym. Chem.,2018,9, 3238–3247.

17. Shuangshuang Zhang, Yasuyuki Tezuka,Zhengbiao Zhang*, Na Li, Wei Zhang* and Xiulin Zhu. Recent advances in the construction of cyclic grafted polymers and their potential applications.Polym. Chem.,2018,9, 677–686. Perspective.

18. Xiaodong Liu, Yuanyuan Ni, Jian Wu, Hongjuan Jiang,Zhengbiao Zhang*, Lifen Zhang,* Zhenping Cheng* and Xiulin Zhu. A sustainable photocontrolled ATRP strategy: facile separation and recycling of a visible-light mediated catalyst fac-[Ir(ppy)3].Polym. Chem.,2018,9, 584–592.

19. Xue Gu, Liuqiao Zhang, Ying Li, Wei Zhang, Jian Zhu,Zhengbiao Zhang*, Xiulin Zhu, Facile Synthesis of Advanced Gradient Polymers with Sequence Control Using Furan-Protected Maleimide as a Comonomer.Polym. Chem.,2018,9, 1571–1576.

20. Zhihao Huang, Junfei Zhao, Zimu Wang, Fanying Meng, Kunshan Ding, Xiangqiang Pan, Nianchen Zhou, Xiaopeng Li,Zhengbiao Zhang*, Xiulin Zhu. Combining Orthogonal Chain End Deprotections and Thiol-Maleimide Michael Coupling: Engineering Discrete Oligomers through Iterative Growth Strategy.Angew. Chem. Int. Ed.2017,56, 13612–13617.

21. Yuxuan Ji, Liuqiao Zhang, Xue Gu, Wei Zhang, Nianchen Zhou,Zhengbiao Zhang,*and Xiulin Zhu. Sequence-Controlled Polymers with Furan-Protected Maleimide as a Latent Monomer.Angew. Chem. Int. Ed.2017,56, 2328–2333.

22. Wei Chen, Yanyan Zhou, Ying Li, Jun Sun, Xiangqiang Pan, Qian Yu, Nianchen Zhou,Zhengbiao Zhang*and Xiulin Zhu.Shape-memory and self-healing polyurethanes based on cyclic poly(ε-caprolactone).Polym. Chem.,2016, 7, 6789–6797.

23. Junfei Zhao, Yanyan Zhou, Yu Zhou, Nianchen Zhou, Xiangqiang Pan,Zhengbiao Zhang* and Xiulin Zhu. A straightforward approach for the one-pot synthesis of cyclic polymers from RAFT polymers via thiol–Michael addition.Polym. Chem.,2016, 7, 1782–1791.

24. Chunlai Ding, Caiwei Fan, Ganquan Jiang, Xiangqiang Pan,Zhengbiao Zhang*,Jian Zhu* and Xiulin Zhu. Photocatalyst-Free and Blue Light-Induced RAFT Polymerization of Vinyl Acetate at Ambient Temperature.Macromolecular Rapid Communications.2015,36, 2181–2185.

25. Zhiwei Lin, Pengtao Lu, Xinfei Yu, Wen-Bin Zhang, Mingjun Huang, Kan Wu, Kai Guo, Chrys Wesdemiotis, Xiulin Zhu,Zhengbiao Zhang*, Kan Yue* and Stephen Z. D. Cheng*. Sequential “Click” Synthesis of “Nano-Diamond-Ring-like” Giant Surfactants Based on Functionalized Hydrophilic POSS/C60 Tethered with Cyclic Polystyrenes.Macromolecules2014,47, 4160–4168.

26. Zhihao Huang,Yanyan Zhou,Zimu Wang,Ying Li,Wei Zhang,Nianchen Zhou,Zhengbiao Zhang^*andXiulin Zhu^*. Recent AdvancesofCuAAC ClickReactionInBuilding Cyclic Polymer.Chinese Journal of Polymer Science2017,35, 317–341. Review article.

27. Zhaoxiong Cai, Weihong Lu, Feng Gao, Xiangqiang Pan, * Jian Zhu,Zhengbiao Zhang*Xiulin Zhu*.Diselenide-Labeled Cyclic Polystyrene with Multiple Responses: Facile Synthesis, Tunable Size, and Topology.Macromol. Rapid Commun.2016,37, 865–871.

28. Shuangshuang Zhang, Lu Yin, Wei Zhang*,Zhengbiao Zhang* and Xiulin Zhu*. Synthesis of Diverse Cyclic-Brush Polymers with Cyclic Polystyrene as Universal Template via Grafting-from Approach.Polym. Chem.,2016, 7, 2112–2120.

29. Qingqing Liu, Huaqiao Wu, Liuqiao Zhang, Yu Zhou, Wei Zhang, Xiangqiang Pan,Zhengbiao Zhang* and Xiulin Zhu. RAFT polymerization of N-vinylpyrrolidone mediated by cyanoprop-2-yl-1-dithionaphthalate in the presence of a fluoroalcohol: the possibility of altering monomer properties by hydrogen bonding?Polym. Chem.,2016, 7, 2015–2021.

30. Yunshu Wang, Shuangshuang Zhang, Laibing Wang, Wei Zhang*, Nianchen Zhou,Zhengbiao Zhang* and Xiulin Zhu*. The Suzuki coupling reaction as a post-polymerization modification: a promising protocol for construction of cyclic-brush and more complex polymers.Polym. Chem.,2015,6, 4669–4677.

31. Feng Gao, Xiangqiang Pan,* Jian Zhu,Zhengbiao Zhang*, Wei Zhang and Xiulin Zhu. Facile synthesis of well-defined redox responsive diselenide-labeled polymers via organoseleniummediated CRP and aminolysis. Polym. Chem.,2015,6,1367–1372.

32. Caiwei Fan, Chunlai Ding, Xiangqiang Pan,Zhengbiao Zhang*, Jian Zhu*, and Xiulin Zhu. A Straightforward Method For Preparing Well-Defined Responsive Diselenide-containing Polymers Based on ATRP.Macromolecular Rapid Communications.2015,36, 903–908.

33. Junfei Zhao, Yanyan Zhou, Yiwen Li, Xiangqiang Pan, Wei Zhang, Nianchen Zhou, Ke Zhang,Zhengbiao Zhang*and Xiulin Zhu*, Modular Construction of Macrocycle-based Topological PolymersviaHigh-Efficient Thiol Chemistry,Polym. Chem.,2015,6,2879–2891.

34. Huaqiao Wu, Yingbo Wan, Wenxiang Wang, Yong Wang, Nianchen Zhou, Wei Zhang, Xiaohong Li,*Zhengbiao Zhang,* Xiulin Zhu, Hydrogen Bonding Promoting Controlled Radical Polymerization of 2-Vinyl Pyridine: Supramonomer for A Better Control,Polym. Chem.,2015,6, 2620–2625.

35. Feng Gao, Xiangqiang Pan, Jian Zhu, Zhengbiao Zhang, Wei Zhang, Xiulin Zhu Diselenocarbamates, Novel Initiators in ATRP of Styrene,J. Polym. Sci., Part A: Polym. Chem.2015,53, 1927–1933.

36. Yuwei Gu, Junfei Zhao, Qingqing Liu, Xiangqiang Pan, Wei Zhang,Zhengbiao Zhang*, Xiulin Zhu*, Zero valent metal/RAFT agent mediated CRP of functional monomers at room temperature: a promising catalyst system for CRP.Polym. Chem.,2015,6, 359–363.

37. Yiwen Li, Hao Su, Xueyan Feng, Kan Yue, Zhao Wang, Zhiwei Lin, Xiulin Zhu, Qiang Fu,Zhengbiao Zhang*, Stephen Z. D. Cheng*, Wen-Bin Zhang*. Precision synthesis of macrocyclic giant surfactants tethered with two different polyhedral oligomeric silsesquioxanes at distinct ring locations via four consecutive click reactions.Polym. Chem.,2015,6, 827–837.

38. Yang Wu, Yanyan Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan,Zhengbiao Zhang*, Xiulin Zhu*. Fast conversion of terminal thiocarbonylthio group of RAFT polymer to clickable thiol group via the versatile sodium azide.Polym. Chem.,2014,5, 5546–5550.

39. Wenxiang Wang, Junfei Zhao, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiangqiang Pan,Zhengbiao Zhang* and Xiulin Zhu* Reversible Deactivation Radical Polymerization in the Presence of Zero-Valent Metals: from Components to Precise Polymerization.Polym. Chem.2014,5, 3533–3546. Review Article.

40. Yang Wu, Junfei Zhao, Xiaofei Zhang, Jian Zhu, Wei Zhang,Zhengbiao Zhang* and Xiulin Zhu* Zero-valent metal catalyzed removal of thiocarbonylthio end groups from RAFT-made polystyrene: producing controllable bimodal molecular weight distribution.Polym. Chem.2014,5, 1992–1998.

41. Zhigui Zheng, Wenxiang Wang, Yuan Zhou,Zhengbiao Zhang* and Xiulin Zhu*. Manganese(III) acetylacetonate initiated RAFT olymerizations: an alternative and versatile RAFT nitiator.Polym. Chem.2014,5, 37–42.

42. Ye Cai, Jinjie Lu, Feng Zhou, Xiaoji Zhou, Nianchen Zhou*,Zhengbiao Zhang*, Xiulin Zhu* Cyclic Amphiphilic Random Copolymers Bearing Azobenzene Side Chains: Facile Synthesis and Topological Effects on Self-Assembly and Photoisomerization.Macromol. Rapid Commun.2014,35, 901−907.

43. Yuwei Gu, Junfei Zhao, Qingqing Liu, Nianchen Zhou,Zhengbiao Zhang*, Xiulin Zhu*. Zero-valent iron (Fe(0)) mediated RAFT miniemulsion polymerization: a facile approach for the fabrication of Fe(0)-encapsulated polymeric nanoparticlesPolym. Chem.,2014,5, 4215−4218.

44. Wenxiang Wang, Junfei Zhao, Huali Yu, Nianchen Zhou,Zhengbiao Zhang*, Xiulin Zhu*. Simultaneously improving controls over molecular weight andstereoregularity of Poly(4-vinylpyridine) via a hydrogen bonding-facilitated controlled radical polymerization.Polymer2013,54, 3248–3253.

45. Xiaofei Zhang, Yang Wu, Jun Huang, Xuelang Miao,Zhengbiao Zhang*, Xiulin Zhu*. Copper(0)-Mediated Radical Polymerization Of Styrene At Room Temperature.Chinese.J. Polym. Sci.2013,31,702–712.

46. Xiaoji Zhou, Wenxiang Wang, Huali Yu, Junfei Zhao,Zhengbiao Zhang*and Xiulin Zhu*. Hydrogen bonding assisted reversible-deactivation radical copolymerization of 4-vinylpyridine and styrene: a facile approach for adjusting polymerization behavior, polymer composition.Polym. Chem.2013,4,3575–3581.

47. Xiaofei Zhang, Wenxiang Wang, Kai Guo, Chrys Wesdemiotis,Zhengbiao Zhang*, Xiulin Zhu*. Zero-valent metal catalyzed radical-induced adjustable removal/modification of thiocarbonylthio end groups of RAFT polymer at ambient temperature.Polym. Chem.2013,4,637–644.

48. Yiyu Zhan,Zhengbiao Zhang*, Xiangqiang Pan, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. A Cyclic Selenium-Based Reversible Addition-Fragmentation Chain Transfer Agent Mediated Polymerization of Vinyl Acetate.J. Polym. Sci., Part A: Polym. Chem.2013,51,1656–1663.

49. Wenxiang Wang, Junfei Zhao, Wei Zhang, Jian Zhu,Zhengbiao Zhang*, Xiulin Zhu*. Ligand-Free SET-DTLRP of MMA at Room Temperature.J. Polym. Sci., Part A: Polym. Chem.2013,51,1872–1879.

50. Xing Zhu, Nianchen Zhou*, Jian Zhu,Zhengbiao Zhang*, Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*. High-Effi ciency Preparation of Macrocyclic Polymers via a Circulatory Extraction-Cyclization Strategy.Macromol. Chem. Phys.2013,214, 1107–1113.

51. Xing Zhu, Nianchen Zhou*, Jian Zhu,Zhengbiao Zhang*, Wei Zhang, Zhenping Cheng, Yingfeng Tu, Xiulin Zhu*.A High-Efficiency Strategy for Synthesizing Cyclic Polymers of Methacryates in One Pot.Macromol. Rapid Commun.2013,34, 1014–1019.

52. Wenxiang Wang,Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Xiulin Zhu*. Favorable hydrogen bonding in room-temperature Cu(0)-mediated controlled radical polymerization of 4-vinylpyridine.Polym. Chem.2012,3,2731–2734.

53. Junfei Zhao, Wenxiang Wang, Liangjiu Bai, Lili Zhou, Zhenping Cheng,Zhengbiao Zhang*, Xiulin Zhu*. Reversible-deactivation radical polymerizationmediated by CuSO₄∙5H₂O: an alternative and promising copper(II)-based catalyst.Polym. Chem.2012,3,3220–3223.

54. Lili Zhou,Zhengbiao Zhang*, Wenxiang Wang, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiulin Zhu*. Zero-Valent Bimetallic Iron/Copper Catalyzed SET-LRP: A Dual Activation by Zero-Valent Iron.J. Polym. Sci., Part A: Polym. Chem.2012,50,936–943.

55. Wenxiang Wang,Zhengbiao Zhang*, Yang Wu, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. Ligand-Free Cu(0)-Mediated Controlled Radical Polymerization of Methyl Methacrylate at Ambient Temperature.J. Polym. Sci., Part A: Polym. Chem.2012,50,711–719.

56. Huali Yu,Zhengbiao Zhang*, Zhenping Cheng, Jian Zhu, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. ATRP of Styrene Catalyzed by Elemental Fe(0) and Br2: An Easy and Economical ATRP Process.J. Polym. Sci., Part A: Polym. Chem.2012,50,2182–2187.

57. Huali Yu, Yang Wu, Jinlong Gao, Wenxiang Wang,Zhengbiao Zhang*, Xiulin Zhu*. Copper(0)-Mediated Radical Copolymerization of Vinyl Acetate and Acrylonitrile in DMSO at Ambient Temperature.J. Polym. Sci., Part A: Polym. Chem.2012,50,4983–4989.

58. Huali Yu, Qifeng Chen,Zhengbiao Zhang*, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. 60Co γ-irradiation-initiated RAFT polymerization of VAc at room temperature.React. Funct. Polym.2012,72, 153–159.

59. Lili Zhou,Zhengbiao Zhang*, Zhenping Cheng, Nianchen Zhou, Jian Zhu, Wei Zhang, Xiulin Zhu*. Fe(0) Powder/CuBr2-Mediated “Living”/Controlled Radical Polymerization of Methyl Methacrylate and Styrene at Ambient Temperature.Macromol. Chem. Phys.2012,213,439–446.

60. Qin Zhang,Zhengbiao Zhang*Wenxiang Wang, Jian Zhu, Zhenping Cheng, Nianchen Zhou, Wei Zhang, Xiulin Zhu*. SET-RAFT of MMA Mediated by Ascorbic Acid-Activated Copper Oxide.J. Polym. Sci., Part A: Polym. Chem.2012,50,1424–1433.