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姓名：曾小庆 职称：教授、博士生导师 部门：化学学院 联系方式： Email: xqzeng@suda.edu.cn 课题组网站 |
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学历及学术经历：
1979
年8月出生于湖北公安县。
2002
年毕业于武汉大学环境化学系，获学士学位；2007年毕业于中国科学院北京化学研究所，分子动态与稳态结构国家重点实验室，获博士学位，导师王殿勋教授；2008年加拿大New Brunswick大学无机化学系博士后；2009年获德国洪堡奖学金(Alexander von Humboldt Stiftung)在Bergische Universitaet Wuppertal著名氟化学家Helge Willner教授课题组从事含氟小分子光谱探测与表征研究；2011年获德国科学基金会(DFG)独立项目资助。2013年受聘于www.优德88.cpm 材化部，物理化学研究所特聘教授，博士生导师。2014年获国家自然科学基金优秀青年基金。
迄今为止，已在国际核心期刊上发表署名论文80余篇，其中近一半为第一作者。自2009年起，以第一或通讯作者接连在Angew. Chem. Int. Ed. (8篇)，J. Am. Chem. Soc. (2篇), Chem. Eur. J.，Chem. Comm.，Inorg. Chem. 等权威化学期刊发表多篇研究论文，其中发表在Angew. Chem. Int. Ed.上的论文屡次被选为VIP、hotpaper、或封面文章，并多次被国际同行以highlight的形式在Angew. Chem. Int. Ed.上撰写全文评论，在小分子与自由基研究领域建立了独特的研究体系与方法。目前主持国家自然科学基金优秀青年基金、自然科学基金面上项目一项。
研究领域：
研究方向主要包括：教科书式原型小分子的低温合成、分离与表征；亚稳态含能化合物的合成、分子结构与构象以及分解反应；主族元素多键化合物的低温合成与光化学反应；关键自由基反应中间体的产生、光谱捕捉、结构、反应和相关机理的实验与理论探索；新型稳定α-oxo氮烯双自由基的结构与反应；以及稳定自由基在介质中的物理化学行为研究。
课题组网站
：http://web.suda.edu.cn/xqzeng/index.html
近五年代表性论文：
[1] Zeng, X. Q.;* Li, H. M.; Sun, H. L.; Beckers, H;* Willner, H.; Schaefer III,H. F.*
SN2P2: A neutral five-membered sulfur-pnictogen(III) ring.
Angew. Chem. Int. Ed.2014, DOI: 10.1002/anie.201409868.
[2] Zeng, X. Q.;* Antognini, A. F.; Beckers, H;* Willner, H.
Isomers of disulfur dinitride, S2N2.
Angew. Chem. Int. Ed.2014, DOI: 10.1002/anie.201407538.
[3] Zeng, X. Q.;* Beckers, H.;* Willner, H.; Neuhaus, P.; Grote, D.; Sander, W.
Photochemistry of matrix isolated trifluoromethylsulfonyl azide, CF3SO2N3.
J. Phys. Chem. A2014, DOI: 10.1021/jp506243s.
[4] Zeng, X. Q.;* Beckers, H.; Seifert, J.; Banert, K.*
The photochemical and thermal decomposition of azidoacetylene in the gas phase, solid matrix, and solutions.
Eur.J. Org. Chem.2014, 4077–4082.
[5] Zeng, X. Q.;* Beckers, H.;* Willner, H.
The iminyl radical O2SN.
Angew.Chem. Int. Ed.2013, 52, 7981–7984.
[6] Zeng, X. Q.;* Beckers, H.;*Willner, H.
The novel iminyl radical O2SN.
Angew. Chem. Int. Ed.2013,DOI: 10.1002/anie.201302968.
[7] Zeng, X. Q.;* Beckers, H.;* Willner, H.
Thermally persistent fluorosulfonyl nitrene and unexpected formation of fluorosulfonyl radical.
J. Am. Chem. Soc.2013,135,2096–2099.
[8] Zeng, X. Q.;* Bernhardt, E.; Beckers, H.;* Banert, K.; Hagedorn, M.; Liu, H.
Formyl azide: properties and solid-state structure.
Angew. Chem. Int. Ed.2013,52,3503–3506.Hot paper.
[9] Zeng, X. Q.;* Beckers, H.; Willner, H.; Stanton, J.F.*
Fascinating diazirinone (N2CO), a violet gas.
Eur. J. Inorg. Chem.2012,3403–3409.Front cover.
[10] Zeng, X.Q.;* Beckers, H.; Willner, H.; Francisco, J. S.*
Experimental observation of the 16-electron SPN, SNP, and cyclic PSN.
Angew. Chem. Int. Ed.2012,51,3334–3339.Inside cover; highlighted as “OPN and SPN:
Small molecules with great potential”byAngew. Chem. Int. Ed.2012, 51, 5541–5542.
[11] Zeng, X. Q.; Beckers, H.;* Neuhaus, P.; Grote, D.; Sander, W.
Elusive fluoro sulfinyl nitrite produced by photolysis of matrix-isolated FS(O)2N.
Z. Anorg. Allg. Chem.2012,638, 526–533.
[12] Zeng, X. Q.; Beckers, H.;* Willner, H.
Elusive O=PºN, a rare example of phosphorus σ2λ5-coordination.
J. Am. Chem. Soc.2011,133, 20696–20699.JACS spotlight;highlighted as “OPN and SPN: Small molecules with great potential”byAngew. Chem. Int. Ed.2012, 51, 5541–5542.
[13] Zeng, X.Q.; Beckers, H.;* Willner, H.;* Stanton, J. F.
Elusive diazirinone, N2CO.
Angew. Chem. Int. Ed.2011,50, 1720–1723.Very Important Paper (VIP);
highlighted as “The demise and revival of diazirinone”byAngew. Chem. Int. Ed.2011, 50,2677–2678.
[14] Zeng, X.Q.; Beckers, H.;* Willner, H.*
Matrix isolation of two isomers of N4CO.
Angew. Chem. Int. Ed.2011,50, 482–485.Highlighted byAngew. Chem. Int. Ed.2011, 50, 2677–2678.
[15] Zeng, X. Q.; Beckers, H.;* Willner, H.;* Grote, D.; Sander, W.
The missing link: Triplet fluorocarbonyl nitrene FC(O)N.
Chem. Eur. J.2011,17,3977–3984.
[16] Zeng, X. Q.;* Beckers, H.; Bernhardt, E.; Willner, H.
Synthesis and characterization of sulfuryl diazide, O2S(N3)2.
Inorg.Chem.2011,50, 8679–8684.
[17] Zeng, X.Q.;* Bernhardt, E.; Beckers, H.; Willner, H.
Synthesis and characterization of the phosphorus triazides OP(N3)3and SP(N3)3.
Inorg. Chem.2011,50, 11235–11241.
[18] Zeng, X. Q.; Gerken,M.;* Beckers, H.; Willner, H.*
Synthesis and characterization of carbonyl diazide, OC(N3)2.
Inorg. Chem.2010,49,9694–9699.Highlighted as “Explosive carbonyl diazide safely made” byC&EN2010,11, 34, andAngew. Chem. Int. Ed.2011, 50, 2677–2678.
[19] Zeng, X. Q.; Gerken, M.; Beckers, H.; Willner,H.*
Spectroscopic and structural studies of difluorophosphoryl azide, difluoro phosphoryl isocyanate, and difluorophosphoric acid anhydride.
Inorg. Chem.2010,49, 3002–3010.
[20] Zeng, X. Q.; Beckers, H.; Willner, H.;* Berger, R. J. F.; Hayes, S. A.;Mitzel, N.
Structure and conformational properties of difluoro(azido)phosphane.
Eur.J. Inorg. Chem.2011, 895–905.
[21] Zeng, X. Q.;Gerken, M.;*Beckers, H.; Willner, H.
Anomeric effects in sulfonyl compounds: an experimental and computational study of fluorosulfonyl azide, FSO2N3, and trifluoromethylsulfonyl azide, CF3SO2N3.
J. Phys. Chem. A2010,114,7624–7630.
[21] Zeng, X. Q.;Beckers, H.;Willner, H.;* Lehmann, C. W.
Bis(methanesulfonyl) peroxide: Spectroscopic, structural, and thermal properties
Z. Anorg. Allg. Chem.2010,636, 2447–2453.
[22] Zeng, X. Q.; Beckers, H.; Willner, H.*
Difluoro-λ5-phosphinonitrile F2P≡N: matrix isolation and photoisomerization into FP=NF.
Angew. Chem. Int. Ed.2009,48, 4828–4831.Very Important Paper (VIP); highlighted as “Stabilized transient R2PN species” byAngew. Chem. Int. Ed.2013,
52, 3068–3070.
[23] Zeng, X. Q.; Beckers, H.; Willner, H.;* Neuhaus,P.; Grote, D.; Sander, W.
Difluoro phosphoryl nitrene, F2P(O)N: matrix isolation and unexpected rearrangement to F2PNO.
Chem. Eur. J.2009,15,13466–13473.
[24] Zeng, X. Q.; Beckers, H.; Willner, H.*
Photoisomerization of matrix isolated F2CS intocisandtransFCSF.
Chem. Comm.2009, 5162–5164.
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