姓名:万小兵 职称:教授、博士生导师 联系方式: Tel:0512-65883276 Email:wanxb@suda.edu.cn 课题组网站 |
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学历及学术经历
:
万小兵,理学博士,江苏泰州人。
1997
年
7
月于南京大学化学化工学院获学士学位,
1998
年
9
月至
2001
年
7
月,南京大学化学系攻读硕士学位,从事超分子化学的研究。
2001
年
9
月至
2005
年
7
月,中国科学院上海有机化学研究所攻读博士学位,系统研究了
Ru/Rh
催化的不对称催化氢化反应,合成了一系列价格低廉、对映选择性高的手性双磷配体。
2005
年
7
月进入北京大学从事
Pd
催化的
C–H
键活化研究,取得了原创性的研究结果。
2007
年
7
月进入www.优德88.cpm 工作,任职副教授。
2012
年破格聘为研究员,
2014
年遴选为博士生导师.主要从事绿色氧化反应,多组分反应,氟化学等领域的研究。迄今为止,已在
JACS
,
Angew. Chem.
,
Org. Lett.
,
JOC
,
Chem. Commun.
,
Chem. Eur. J.
和
Adv. Synth. Cat.
等国际一流研究刊物发表论文数十篇,得到国内外同行的广泛关注与引用(引用近千次)。申请中国发明专利
12
项,已经授权
4
项。
研究领域 : 绿色氧化反应,多组分反应,氟化学。发展绿色、环境友好的反应体系,合成具有重要的应用价值和具有生物活性的分子。 代表性论文
1.Jie Zhang, Jiewen Jiang, Dongmei Xu, Qiang Luo, Hongxiang Wang, Jijun Chen, Huihuang Li, Yaxiong Wang, and
Xiaobing Wan*
I
nterception of Co-Based Carbene-Radical with α-Aminoalkyl Radicals: A New Tandem Reaction to Constructβ-Ester-γ-Amino Ketone.Angew. Chem. Int. Ed.2014,
DOI: 10.1002/anie.201408874.
2.
Zhaojun Liu, Jie Zhang, Shulin Chen, Erbo Shi, Yuan Xu, andXiaobing Wan,*
Cross Coupling of Acyl and Aminyl Radicals: Direct Amides Synthesis Catalyzed by Bu4NI Using TBHP as an Oxidant.Angew. Chem. Int. Ed.2012,51, 3231–3235.
3.
Xiaobing Wan
, Dong Xing, Zhao Fang, Bijie Li, Fei Zhao, Keya Zhang, Liping Yang, and Zhangjie Shi.* Multiple Deprotonations and Deaminations of Phenethylamines. An Unprecedented Apporach to Synthesize Pyrroles.J. Am. Chem. Soc.2006,128, 12046–12047.
4.
Xiaobing Wan
, Zhongxun Ma, Bijie Li, Keya Zhang, Shaokui Cao, Shiwei Zhang and Zhangjie Shi.* Highly Selective C-H Functionalization/Halogenation of Acetanilide.J. Am. Chem. Soc.2006,128, 7416–7417.
5.
Zhang, Jie; Shao, Ying;* Wang, Hongxiang; Luo, Qiang; Chen, Jijun; Xu, Dongmei ;*Wan, Xiaobing*Dual Roles of Sulfonyl Hydrazides: A Three-Component Reaction To Construct Fully Substituted Pyrazoles Using TBAI/TBHP.Org. Lett.,2014,16, 3312–3315.
6.
Zhang, Feng; Du, Peng; Chen, Jijun; Wang, Hongxiang ; Luo, Qiang
Wan, Xiaobing,*
Co-Catalyzed Synthesis of 1,4-Dicarbonyl Compounds Using TBHP Oxidant
.
Org. Lett.
,2014,16, 1932
–
1935.
7.
Chao Zhang, Chunmei Liu, Ying Shao, Xiaoguang Bao,* andXiaobing Wan,*
Nucleophilic Attack of alpha- Aminoalkyl Radicals on Carbon-Nitrogen Triple Bonds to Construct alpha- Amino Nitriles: An Experimental and Computational Study.
Chem. Eur. J.
2013
,
19
, 17917–17925.
8.
Jie Zhang, Jiewen Jiang, Yuling Li, andXiaobing Wan,* Iodide-Catalyzed Synthesis of N-Nitrosamines via C-N Cleavage of Nitromethane.J. Org. Chem.2013,78, 11366−11372.
9.
Jie Zhang, Jiewen Jiang, Yuling Li, Yun Zhao, andXiaobing Wan,* A New Strategy for the Construction of alpha-Amino Acid Esters via Decarboxylation.Org. Lett.,2013,15,
3222
−
3225.
10.
Wei Wei, Ying Shao, Huayou Hu, Feng Zhang, Chao Zhang, Yuan Xu, andXiaobing Wan,*
Coupling of Methyl Ketones and Primary or Secondary Amines Leading to α-Ketoamides.
J. Org. Chem.
,
2012
,
77
, 7157–7165.
11.
Erbo Shi, Ying Shao, Shulin Chen, Huayou Hu, Zhaojun Liu, Jie Zhang, andXiaobing Wan,* Tetrabutylammonium Iodide Catalyzed Synthesis of Allylic Ester with tert-Butyl Hydroperoxide as an Oxidant,
Org. Lett.
,2012,14, 3384-3387.
12.
Shulin Chen, Yuan Xu, andXiaobing Wan,*Direct Condensation of Sulfonamide and Formamide: NaI-Catalyzed Synthesis of N-Sulfonyl Formamidine Using TBHP as Oxidant.
Org. Lett.
,2011,13, 6152–6155
.
13.
Wei Wei, Chao Zhang, Yuan Xu,Xiaobing Wan,*Synthesis of tert-Butyl Peresters from Aldehydes by Bu4NI-catalyzed Metal-free Oxidation and Its Combination with the Kharasch–Sosnovsky Reaction.Chem. Commun.,2011,47, 10827-10829.
14.
Hong Li, Yuan Xu, Erbo Shi, Wei Wei, Xiangqiang Suo,Xiaobing Wan,*
Synthesis of Arylketones by Ruthenium-Catalyzed Cross-Coupling of Aldehydes with Arylboronic Acids
.
Chem. Commun.
,2011,47, 7880-7882
.
15.
Shulin Chen, Zhaojun Liu, Erbo Shi, Long Chen, Wei Wei, Hong Li, Yannan Cheng, andXiaobing Wan,*
Ruthenium-Catalyzed Oxidation of Alkenes at Room Temperature: A Practical and Concise Approach toα-Diketones.
Org. Lett.,2011,13, 2274-2277
.
16.
Long Chen, Erbo Shi, Zhaojun Liu, Shulin Chen, Wei Wei, Hong Li, Kai Xu andXiaobing Wan,* Bu4NI-Catalyzed C–O Formation via Cross-Dehydrogenative Coupling (CDC) Reaction.Chem. Eur. J.2011,17, 4085-4089.
17.
Hong Li, Wei Wei, Yuan Xu, Chao Zhang andXiaobing Wan,* Ru-catalyzed Aerobic Oxidative Coupling of Arylboronic Acids with Arenes.Chem. Commun.,2011, 47, 1497–1499.
18.
Wei Ren, Jinfeng Liu, Long Chen, andXiaobing Wan,* Ruthenium-Catalyzed Alkyne Oxidation with Part-Per-Million Catalyst LoadingsAdv. Synth. Catal.2010,352, 1424–1428.
19.
Wei Ren, Yuanzhi Xia, Shun-Jun Ji, Yong Zhang,Xiaobing Wan,* and Jing Zhao, Wacker-Type Oxidation of Alkynes into 1,2-Diketones Using Molecular Oxygen.Org. Lett.,2009,11, 1841–1844.
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