姓名:汪顺义(WANG SHUN-YI) 职称:教授、博士生导师 联系方式:
Email:shunyi@suda.edu.cn
Tel:15962208862
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1998.9-2002.6 www.优德88.cpm 化学化工学院 学士
(导师:纪顺俊教授)
2002.9-2007.6 www.优德88.cpm 化学化工学院 博士
(导师:纪顺俊教授)
2005.12-2006.12 新加坡南洋理工大学助理研究员
(Research Associate, 新加坡科学院院士、马来西亚科学
院院士、中国千人计 划 Prof. Teck-Peng Loh)
2007.8-2011.2 新加坡南洋理工大学博士后研究员
(Research Fellow, 新加坡科学院院士、马来西亚科学院
院士、中国千人计划 Prof. Teck-Peng Loh)
2011.3-2011.12 德国慕尼黑大学博士后研究员
(Research Fellow, 德国、法国、巴伐利亚科学院院士 Prof. Paul Knochel)
2012.1-2015.06 www.优德88.cpm 材料与化学化工学部副教授
2015.06-至今 www.优德88.cpm 材料与化学化工学部教授
学术经历:2003年至今,在Nature Commun.,Chem. Sci.,ACS Catal.,Org. Lett.,Org.Chem. Front.,Chem. Commun.,Adv. Synth. Catal., Chem.Eur. J., J. Org. Chem.等期刊上以第一作者、通讯联系人发表论文140余篇。目前完成国家自然科学基金面上项目2项、国家自然科学基金应急项目1项、江苏省教育厅重大项目1项、国家自然科学基金青年基金1项、江苏省自然科学基金青年基金1项、江苏省有机合成重点实验室开放基金1项。
获奖:2006年-2007年度苏州市自然科学论文一等奖;2007年www.优德88.cpm 优秀博士论文、2008年江苏省优秀博士论文、2009年全国百篇优秀博士论文提名奖;2010年第六届亚欧金属促进反应会议优秀墙报奖;作为主要完成人参与的项目“功能性有机分子的合成、性质及应用研究”获得2010年中国石油和化学工业协会科技进步二等奖、2013年教育部高等学校www.优德88.cpm 优秀成果奖(科学技术)自然科学奖二等奖。2018年获得Thieme Chemistry Journals Award,2020年入选www.优德88.cpm 仲英青年学者,2021年入选苏州市工业园区科技创新领军人才,2023年入选江苏省青蓝工程中青年学术带头人、姑苏创新创业领军人才。
教学经历:担任本科生强化班《Spectroscopic Methods In Organic Chemistry》,《有机化学实验》等课程的教学任务,2013年www.优德88.cpm 第十二届青年教师课堂教学竞赛三等奖。
研究领域:有机硫族化学;自由基参与的新反应研究;ADC抗体偶联药物接头;含硫功能新材料。
代表性论文及参编著作
回国工作后发表的部分论文
1. Fei Wang, Ying Chen, Weidong Rao, Lutz Ackermann* andShun-Yi Wang*
Efficient preparation of unsymmetrical disulfides by nickel-catalyzed reductive coupling strategy
Nature Communications2022,13, 2588.
2. Ji-Min Cao, Wei-Chen Zhu, Xin-Yu Liu, Weidong Rao, Shu-Su Shen, Dao-peng Sheng, andShun-Yi Wang*
Simultaneous Preparation of Sulfides/Selenides and Sulfones via Synergistic Nickel-Catalyzed Reductive Coupling and SN2 Reaction
Organic Letters2023,25, 9207−9212.
3. Wang Chen, Xin-yu Liu, Daopeng Sheng, Yi-Fan Jiang, Weidong Rao, Shu-Su Shen, Zhao-Ying Yang andShun-Yi Wang*
Access to disulfides through ligand-controlled nickel-catalyzed dithiosulfonate and alkyl halides
Organic Chemistry Fronttiers2024,11,doi.org/10.1039/D3QO01868G.
4. Ying Chen, Fei Wang, Bo-Xi Liu, Wei-Dong Rao andShun-Yi Wang*
A Ni(II)-catalyzed reductive cross-coupling reaction of oxalates and thiosulfonates/selenosulfonates
Organic Chemistry Fronttiers2022,9, 731–736.
5. Fei Wang, Ying Chen, Lutz Ackermann* andShun-Yi Wang*
Efficient preparation of unsymmetrical alkyl–aryl tellurides via a nickel-catalyzed reductive coupling strategy
Organic Chemistry Fronttiers2022,9, 3199-3203.
6. Fei Wang, Ying Chen, Weidong Rao, Shu-Su Shen andShun-Yi Wang*
Cu-catalyzed efficient construction of S (Se)-containing functional organosilicon compounds
Chemical Communications2022,58, 12564–12567.
7. Bo-Xi Liu, Fei Wang, Ying Chen, Wei-Dong Rao, Shu-Su Shen, andShun-Yi Wang*
Visible-Light-Promoted Denitrogenative Ortho-selenylation Reaction of benzotriazinones: Synthesis of ortho-selenylated Benzamides, Ebselen Analogs
Organic Chemistry Fronttiers2022,9, 2418-2423.
8. Yi-Fan Jiang, Wei-Chen Zhu, Xin-Yu Liu, Shi-Yin Tian, Jia-Hui Han, Weidong Rao, Shu-Su Shen, Daopeng Sheng, andShun-Yi Wang*
Synthesis of 1,3-Dibenzenesulfonylpolysulfane (DBSPS) and Its Application in the Preparation of Aryl Thiosulfonates from Boronic Acids
Organic Letters2023,25, 1776−1781.
9. Ping Song, Weidong Rao, Tristram Chivers* andShun-Yi Wang*
Applications of trisulfide radical anion S3•− in organic synthesis
Organic Chemistry Fronttiers2023,10, 3378-3400.
10. Xin-Yu Liu,Shi-Yin Tian,Yi-Fan Jiang,Weidong Rao, andShun-Yi Wang*
Visible Light-Triggered Sulfonylation/aryl migration/desulfonylation and C-S/Se Bond Formation Reaction: 1,2,4-Trifunctionalization of Butenyl Benzothiazole Sulfone with Thiosulfonate/Selenosulfonates
Organic Letters2021,23, 8246−8251.
11. Fei Wang andShun-Yi Wang*
Visible-light-promoted cross-coupling reaction of hypervalent bis-catecholato silicon compounds with selenosulfonates or thiosulfonates
Organic Chemistry Fronttiers2021,8, 1976-1982.
12. Jing-Jing Ai, Bei-Bei Liu, Jian Li, Fei Wang, Cheng-Mi Huang, Weidong Rao, andShun-Yi Wang*
Fe−S Catalyst Generated In Situ from Fe(III)- and S3•−-Promoted Aerobic Oxidation of Terminal Alkenes
Organic Letters2021,23, 4705-4709.
13. Lin Xu, Pei Xu, Yi-Ming Zhu, Weidong Rao andShun-Yi Wang*
NaI/TBHP-promoted reaction of indole-2-thiones with arylsulfonyl hydrazides: construction of achiral axial 3,3’-biindole-2,2’-dibenzenesulfonothioate derivatives
Organic Chemistry Fronttiers2021,8, 5383-5388.
14. Cheng-Mi Huang, Jian Li, Jing-Jing Ai, Xin-Yu Liu, Weidong Rao, andShun-Yi Wang*
Visible-Light-Promoted Cross-Coupling Reactions of Aryldiazonium Salts with S‑Methyl‑d3Sulfonothioate or Se-Methyl‑d3Selenium Sulfonate: Synthesis of Trideuteromethylated Sulfides, Sulfoxides, and Selenides
Organic Letters2020,22, 9128-9132.
15. Fei Wang, Bo-Xi Liu, Weidong Rao, andShun-Yi Wang*
Metal-Free Chemoselective Reaction of Sulfoxonium Ylides and Thiosulfonates: Diverse Synthesis of 1,4-Diketones, Aryl Sulfursulfoxonium Ylides, and β‑Keto Thiosulfones Derivatives
Organic Letters2020,22, 6600-6604.
16. Jian Li, Xin-Er Yang, Shan-Le Wang, Long-Long Zhang, Xiao-Zhou Zhou,Shun-Yi Wang,*and Shun-Jun Ji*
Visible-Light-Promoted Cross-Coupling Reactions of 4‑Alkyl-1,4-dihydropyridines with Thiosulfonate or Selenium Sulfonate: A Unified Approach to Sulfides, Selenides, and Sulfoxides
Organic Letters2020,22, 4908-4913.
17. Jing-Hao Li, Qi Huang, Weidong Rao,Shun-Yi Wang,* and Shun-Jun Ji*
Trisulfur Radical Anion (S3•−) Involved Sulfur Insertion Reaction of 1,3-Enynes: Sulfide Sources Control Chemoselective Synthesis of 2,3,5-trisubstituted Thiophenes and 3-thienyl Disulfides
Chemical Communications2019,55, 7808—7811.
18. Can Liu,Yi Fang,Shun-Yi Wang,* and Shun-Jun Ji*
RhCl3×3H2O-CatalyzedLigand-EnabledHighly Regioselective Thiolation of Acrylic Acids
ACS Catalysis2019,9, 8910−8915.
19. Yi Fang, Can Liu, Weidong Rao, Shun-Yi Wang* and Shun-Jun Ji*
Metal-free Synthesis of N-(Carboselenoate) benzimidazolones by Cascade Cyclization of ortho-Diisocyanoarenes and Selenosulfonates
Organic Letters2019,21, 7687-7691.
20. Jian Li,Weidong Rao,Shun-Yi Wang,*,and Shun-Jun Ji*
Nickel-Catalyzed Defluorinative Reductive Cross-Coupling Reaction ofgem-Difluoroalkenes with Thiosulfonate or Selenium Sulfonate
The Journal of Organic Chemistry2019,84, 11542-11552.
21. Jian Li, Shun-Yi Wang,* and Shun-Jun Ji*
Nickel-Catalyzed Thiolation/ and Selenylation of Cycloketone Oxime Esters with Thiosulfonate or Selenium sulfonate
The Journal of Organic Chemistry2019,84,16147-16156.
22. Fei Wang, Pei Xu, Bei-Bei Liu,Shun-Yi Wang*and Shun-Jun Ji*
Pd-Catalyzed Multicomponent Reaction of Sulfonyl azide, Primary amines and Methyl α-lsocyanoacetates: Highly Efficient Synthesis of Tetrasubstituted Imidazolidone Derivatives
Organic Chemistry Frontiers2019,6, 3754-3758.
23. Pei Xu, Yi-Ming Zhu, Fei Wang,Shun-Yi Wang,*and Shun-Jun Ji*
Mn(III)-Mediated Cascade Cyclization of 3-Isocyano-[1,1'-biphenyl]-2-carbonitrile with Arylboronic Acid: Construction of Pyrrolopyridine Derivatives
Organic Letters2019,21, 683-686.
24. Nan Jiang,Yi Fang,Yue Fang,Shun-Yi Wang*and Shun-Jun Ji*
Iodine Promoted One Pot reaction of pyridin-2-amine with Arylmethyl Ketone and Selenosulfonate: Synthesis of 3-(Alkylselanyl)-2-arylimidazo[1,2-a]pyridine Under Transition-metal Free Conditions
Organic Chemistry Frontiers2019,6, 654-659.
25. Yi Fang, Can Liu, Fei Wang, Rao Ding,Shun-Yi Wang*and Shun-Jun Ji*
Radical-chain reaction of Isocyanides with Selenosulfonates and Water: Facile Synthesis of Selenocarbamates Under Metal-free Conditions
Organic Chemistry Frontiers2019,6, 660-663.
26.
27. Yi Fang, Torben Rogge, Lutz Ackermann,Shun-Yi Wang,*and Shun-Jun Ji*
Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides
Nature Communications2018,9, 2240.(SCI12.353)
28. Rong Zhang, Zheng-Yang Gu,Shun-Yi Wang,*and Shun-Jun Ji*
Co(II)/Ag(I) Synergistically Catalyzed Mono-insertionReaction of Isocyanide to Terminal Alkynes with H2O: Synthesis ofAlkynamidesDerivatives
Organic Letters2018,20, DOI: 10.1021/acs.orglett.8b02516
29. Jing-Hao Li, Qi Huang,Shun-Yi Wang,*and Shun-Jun Ji*
Trisulfur Radical Anion (S3•−) Involved [1+2+2] and [1+3+1] Cycloaddition with Aromatic Alkynes: Synthesis of Tetraphenylthiophene and 2-Benzylidenetetrahydrothiophene Derivatives
Organic Letters2018,20, 4704-4708.
30. Huan Liu, Yi Fang,Shun-Yi Wang,*and Shun-Jun Ji*
TEMPO-catalyzed aerobic oxidative selenium insertion reaction:synthesis of 3-selenylindole derivatives by multicomponent reaction of isocyanides, selenium powder, amines and indoles under transition metal-free conditions
Organic Letters2018,20, 930-933.
31. Fei Wang, Pei Xu,Shun-Yi Wang,*and Shun-Jun Ji*
Cu(II)/Ag(I)-Catalyzed Cascade Reaction of Sulfonylhydrazone with Anthranils: Synthesis of 2-Aryl-3-sulfonyl Substituted Quinoline Derivatives
Organic Letters2018,20, 2204-2207.
32. Zheng-Yang Gu, Rong Zhang,Shun-Yi Wang,*and Shun-Jun Ji*
Cobalt(II)-Catalyzed Bis-isocyanides Insertion Reactions with Boric acids and Sulfonyl AzidesviaNitrene Radical Coupling
Chinese Journal of Chemistry2018,36, 1011-1016.
33. Zheng-Yang Gu,Yuan Liu,Fei Wang,Xiaoguang Bao,*Shun-Yi Wang,*and Shun-Jun Ji*
Cobalt(II)-Catalyzed Synthesis of Sulfonyl GuanidinesviaNitrene Radical Coupling with Isonitriles: A Combined Experimental and Computational Study
ACS Catalysis2017,7, 3893−3899.
34. Yi Fang, Zheng-Lin Zhu, Pei Xu,Shun-Yi Wang,*and Shun-Jun Ji*
Aerobic Radical-Cascade Cycloaddition of Isocyanides, Selenium and Imidamides: Facile Access to 1,2,4-Selenadiazoles under Metal-Free Conditions,Green Chemistry2017,19, 1613-1618.
35. Pei Xu, Fei Wang, Tian-Qi Wei, Ling Yin,Shun-Yi Wang,*and Shun-Jun Ji*
Palladium-catalyzed Incorporation of Two C1 Building Blocks: The Reaction of Atmospheric CO2 and Isocyanides with 2-Iodoanilines Leading to an Synthesis of Quinazoline-2,4(1H,3H)-diones
Organic Letters2017,19, 4484-4487.
36. Zheng-Yang Gu, Jia-Jia Cao,Shun-Yi Wang,*and Shun-Jun Ji*,The Involvement of the Trisulfur Radical Anion in Electron-Catalyzed Sulfur Insertion Reactions: Facile Synthesis of Benzothiazine Derivatives under Transition Metal-free Conditions,Chemical Science2016,7, 4067-4072.
37. Zheng-Yang Gu, Cheng-Guo Liu,Shun-Yi Wang,*and Shun-Jun Ji*Pd-Catalyzed Intramolecular Heck Reaction, C(sp2)−H Activation, 1,4-Pd Migration andAminopalladation:ChemoselectiveSynthesis of Dihydroindeno[1,2,3-kl]acridines and 3-Arylindoles
Organic Letters2016,18, 2379-2382.
38. Zhong-Jian Cai, Fang-Hui Li,Shun-Yi Wang*and Shun-Jun Ji*
Palladium-Catalyzed Cascade Arene/Alkyne Annulation: Synthesis of Fluorene-Benzoxazine Derivatives
Organic Letters2016,18, 4810-4813.
39. Hui-Wen Bai, Zhong-Jian Cai,Shun-Yi Wang,*andShun-Jun Ji*
Aerobic Oxidative Cycloaddition of α-Chlorotosylhydrazones with Arylamines: General Chemoselective Construction of 1,4-Disubstituted and 1,5-Disubstituted 1,2,3-Triazoles under Metal-free and Azide-free Conditions
Organic Letters2015,17,17, 2898-2901.
40. Tong-Hao Zhu,Shun-Yi Wang,*Yang-Qing Tao,andShun-Jun Ji*
Synthesisof Carbodiimides byI2/CHPMediated Cross Coupling Reaction of Isocyanides withAminesunder Metal-free Conditions
Organic Letters2015,17, 1974-1977.
41. Zheng-Yang Gu,‡Tong-Hao Zhu,‡Jia-Jia Cao, Xiao-Ping Xu,Shun-Yi Wang,*and Shun-Jun Ji*
Palladium-catalyzed Cascade Reactionsof Isocyanides with Enaminones: Synthesis of 4-Aminoquinoline Derivatives
ACS Catalysis2014,4, 49-52.Invited paper: Virtual special issue on cascade catalysis.
42. Jia-Jia Cao, Tong-Hao Zhu,Shun-Yi Wang*, Zheng-Yang Gu, Xiang Wang and Shun-Jun Ji*tert-Butyl benzoperoxoate (TBPB) Mediated 2-Isocyanobiaryls Insertion with 1,4-Dioxane: Efficient Synthesis of 6-Alkyl Phenathridines via C(sp3)-H/C(sp2)-H Bond Functionalization
Chemical Communications2014,50, 6439-6442.Front cover picture paper.英国皇家化学学会RSC2015年“TOP1%高被引中国作者”论文。
43. Jia-Jia Cao, Xiang Wang,Shun-Yi Wang*,and Shun-Jun Ji*
Mn(III)-mediated Reactions of 2-Isocyanobiaryl with 1, 3-Dicarbonyl Compounds: Efficient Synthesis of 6-Alkylated and 6-Monofluoro-alkylated Phenanthridines
Chemical Communications2014,50, 12892-12895.
回国工作前发表的部分论文
44. Shun-Yi Wang,†Ping Song,† Li-Yan Chan and Teck-Peng Loh* Total Synthesis of Phytophora Mating Hormoneα1Org. Lett.2010,12, 5166-5169.
45. Shun-Yi Wang, Ping Song, Yen-Jin Chin, and Teck-Peng Loh* A General Strategy for the Introduction of Stereogenic Centers Bearing Methyl Group: Total Synthesis of Sex PheromonesChem.-Asian. J.2011,6, 385-388.
46. Shun-Yi Wangand Teck-Peng Loh* Cu(I)-Tol-BINAP-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents toα,β−Unsaturated EstersChem. Commun.2010,46, 8694-8703.
47. Shun-Yi Wang,Ping Song and Teck-Peng Loh* Excess Phosphine Ligand Plays A Critical Role in The Asymmetric CuI-Catalyzed Conjugate Addition of Grignard Reagents toα,β-Unsaturated EstersAdv. Syn. Catal.2010,352, 3185-3189.
48. Shun-Yi Wang,Chin Yen-Jin, Teck-Peng Loh* Synthesis of C13-C23 fragment of Iriomoteolide-1a.Synthesis2009, 3557-3564.
49. Shun-Yi Wang,Lum, Tze-Keong, Shun-Jun Ji, Teck-Peng Loh* Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to alpha,beta-unsaturated estersAdv. Syn. Catal.2008,350, 673-677.
50. Shun-Yi Wang,Shun-Jun Ji*, Teck-Peng Loh* Cu(I) Tol-BINAP-Catalyzed Enantioselective Michael Reactions of Grignard reagents and Unsaturated EstersJ. Am. Chem. Soc.2007,129, 276-277.