学历及学术经历:

2001年博士毕业于中国科学院化学研究所高分子物理与化学国家重点实验室。2001−2004年德国拜罗伊特大学、英国萨塞克斯大学、英国谢菲尔德大学博士后，2005年加拿大蒙特利尔大学访问学者。2004−2011年，湘潭大学教授，博士生导师。2011年至今，www.优德88.cpm 特聘教授，博士生导师。中国化学会第28届理事会高分子学科委员会委员，科技部国际科技合作计划项目评价专家，科技部高新科技企业评审专家，教育部环境友好化学与应用重点实验室学术委员会委员，国家自然科学基金会评专家，国家自然科学基金委化学学部重点项目中期检查及结题验收专家组成员，IUPAC先进材料与合成研讨会主席。湖南省普通高等学校优秀青年骨干教师，湖南省新世纪121人才工程第二层次人选，江苏省双创人才，江苏省创新团队引进团队核心成员。

本课题组致力于师法自然，效仿生物大分子精密构筑与生命功能，探索高分子材料仿生合成、仿生组装、仿生功能化的新概念、新理论、新策略、新技术。先后承担国家八五科技攻关重点项目1项，国家自然科学基金9项，以及各类省部级科研项目和企业合作项目。率先提出可见光引发可控自由基聚合（中国科学院科技战略咨询研究院发布《2017研究前沿》、《2018研究前沿》化学与材料www.优德88.cpm 领域十大热点前沿之一）、可见光引发聚合诱导自组装、聚合诱导静电自组装（SCI数据库高被引论文），正在孕育成为相关领域发展前沿，被国内外学者誉为标志性成果。培养出站博士后1名，培养毕业博士7名、硕士66名，指导教育部大学生创新性实验计划团队项目2项。1名硕士生获太平洋地区高分子大会奖，1名博士生获省自然科学优秀学术论文一等奖，3名硕士生获省优秀硕士学位论文，6名硕士生获研究生校长奖，1个本科生创新团队荣获国家教育部大学生创新性实验计划优秀奖。

热诚欢迎有共同志趣的本科生、硕士研究生、博士研究生、博士后加盟本研究团队。

研究领域：

绿色精准高分子制备：光聚合反应技术，大分子精密合成，仿生聚合，聚合诱导自组装，聚合诱导静电自组装

高分子仿生功能材料：分子动态组合材料，高分子单链纳米器件，超分子仿生功能材料，液相凝聚纳米器件化

代表性论文：

1. Jie Cai, Xiyu Wang, Yuanyuan Liu, Caihui Luo, Xinhua Lu,Yuanli Cai*.Site-specific polymerization- induced electrostatic self-assembly: Synthesis of highly charged salt-tolerant polyion complex nanoreactors.Macromolecules, 2023, 56, 10153 − 10162.

2. Yuanyuan Liu, Xiyu Wang, Caihui Luo, Jie Cai, Yuting Li, Ying Cao,Yuanli Cai*.L-Histidine salt-bridged monomer preassembly and polymerization-induced electrostatic self-assembly.Macromolecules, 2023, 56, 6655 − 6666.

3. Caihui Luo, Xiyu Wang, Yuanyuan Liu, Jie Cai, Xinhua Lu,Yuanli Cai*.Like-charge PISA: Polymerization-induced like-charge electrostatic self-assembly.ACS Macro Letters, 2023, 12, 1045 − 1051.

4. Weixing Xiong, Xiyu Wang, Yuanyuan Liu, Caihui Luo, Xinhua Lu,Yuanli Cai*.Polymerization-induced electrostatic self-assembly governed by guanidinium ionic hydrogen bonds.Macromolecules, 2022, 55, 7003 − 7012.

5. Kaiwen Yu, Xiyu Wang, Caihui Luo, Ying Cao, Jie Cai, Xinhua Lu,Yuanli Cai*.Two-dimensional polymerization-induced electrostatic self-assembly via a C12-polyelectrolyte lamellar template.Chemical Communications, 2022, 58, 6793 – 6796.

6. Lei Ma, Weixing Xiong, Kaiwen Yu, Xiyu Wang, Ying Cao, Xinhua Lu,Yuanli Cai*.Liquid-phase condensation via macromolecular crowding in polymerization-induced electrostatic self-assembly.ACS Macro Letters, 2021, 10, 1410 − 1415.

7. Chao Li, Ye Wang, Xiyu Wang, Zhanwei Gao, Lei Ma, Xinhua Lu,Yuanli Cai*.Nanostructured multiphase condensation of complex coacervates in polymerization-induced electrostatic self-assembly.ACS Macro Letters, 2021, 10, 780 − 785.

8. Ye Wang, Chao Li, Lei Ma, Xiyu Wang, Kai Wang, Xinhua Lu,Yuanli Cai*.Interfacial liquid-liquid phase separation-driven polymerization-induced electrostatic self-assembly.Macromolecules, 2021, 54, 5577 – 5585.

9. Qingqing Zhao, Qizhou Liu, Chao Li, Lei Cao, Lei Ma, Xiyu Wang,Yuanli Cai*.Noncovalent structural locking of thermoresponsive polyion complex micelles, nanowires, and vesicles via polymerization-induced electrostatic self-assembly using an arginine-like monomer.Chemical Communications,2020, 56, 4954 − 4957.

10. Qizhou Liu, Xiyu Wang, Lei Ma, Kaiwen Yu, Weixing Xiong, Xinhua Lu,Yuanli Cai*.Polymerization-induced hierarchical electrostatic self-assembly: Scalable synthesis of multicompartment polyion complex micelles and their monolayer colloidal nanosheets and nanocages.ACS Macro Letters,2020, 9, 454 − 458.

11. Lei Cao, Qingqing Zhao, Qizhou Liu, Lei Ma, Chao Li, Xiyu Wang,Yuanli Cai*.Electrostatic manipulation of triblock terpolymer nanofilm compartmentalization during aqueous photoinitiated polymerization-induced self-assembly.Macromolecules,2020, 53, 2220 − 2227.

12. Yi Ding, Qingqing Zhao, Lei Wang, Leilei Huang, Qizhou Liu, Xinhua Lu,Yuanli Cai*.Polymerization-induced self-assembly promoted by liquid-liquid phase separation.ACS Macro Letters,2019, 8, 943 − 946.

13. Lei Wang, Yi Ding, Qizhou Liu, Qingqing Zhao, Xinchao Dai, Xinhua Lu,Yuanli Cai*.Sequence-controlled polymerization-induced self-assembly.ACS Macro Letters,2019, 8, 623 − 628.

14. Leilei Huang, Yi Ding, Yajie Ma, Lei Wang, Qizhou Liu, Xinhua Lu,Yuanli Cai*.Colloidal stable PIC vesicles and lamellae enabled by wavelength-orthogonal disulfide exchange and polymerization-induced electrostatic self-assembly.Macromolecules,2019, 52, 4703 − 4712.

15. Yajie Ma, Pan Gao, Yi Ding, Leilei Huang, Lei Wang, Xinhua Lu,Yuanli Cai*.Visible light initiated thermoresponsive aqueous dispersion polymerization-induced self-assembly.Macromolecules,2019, 52, 1033 − 1041.

16. Yi Ding, Meng Cai, Zhigang Cui, Leilei Huang, Lei Wang, Xinhua Lu,Yuanli Cai*.Synthesis of low-dimensional polyion complex nanomaterials via polymerization-induced electrostatic self-assembly.Angewandte Chemie−International Edition,2018, 57, 1053 − 1056.

17. Meng Cai, Yi Ding, Lei Wang, Leilei Huang, Xinhua Lu,Yuanli Cai*.Synthesis of one-component nanostructured polyion complexes via polymerization-induced electrostatic self-assembly.ACS Macro Letters,2018, 7, 208 − 212.

18. Zhigang Cui, Leilei Huang, Yi Ding, Xuechao Zhu, Xinhua Lu,Yuanli Cai*.Compartmentalization and unidirectional cross-domain molecule shuttling of organometallic single-chain nanoparticles.ACS Macro Letters,2018, 7, 572 − 575.

19. Hui Cao, Zhigang Cui, Pan Gao, Yi Ding, Xuechao Zhu, Xinhua Lu,Yuanli Cai*.Metal-folded single-chain nanoparticle: Nanoclusters and self-assembled reduction-responsive sub-5-nm discrete subdomains.Macromolecular Rapid Communications,2017, 38, 1700269.

20. Zhigang Cui, Hui Cao, Yi Ding, Pan Gao, Xinhua Lu,Yuanli Cai*.Compartmentalization of ABC triblock copolymer single-chain nanoparticle via coordination driven orthogonal self-assembly.Polymer Chemistry,2017, 8, 3755 – 3763.

21. Pan Gao, Hui Cao, Yi Ding, Meng Cai, Zhigang Cui, Xinhua Lu,Yuanli Cai*.Synthesis of hydrogen-bonded pore-switchable cylindrical vesicles via visible-light-mediated RAFT room-temperature aqueous dispersion polymerization.ACS Macro Letters,2016, 5, 1327 − 1331.

22. Kaiyi Zhou, Hui Cao, Pan Gao, Zhigang Cui, Yi Ding,Yuanli Cai*.Autocatalytic self-sorting in biomimetic polymer.Macromolecules,2016, 49, 2189 − 2196.

23. Jie Han, Kaiyi Zhou, Xuechao Zhu, Qiuping Yu, Yi Ding, Xinhua Lu,Yuanli Cai*.Chelation-induced polymer structural hierarchy/complexity in water.Macromolecular Rapid Communications,2016, 37, 1275 − 1281.

24. Tao Huang, Zhigang Cui, Yi Ding, Xinhua Lu,Yuanli Cai*.The use of electrostatic association for rapid RAFT synthesis of histamine polyelectrolyte in aqueous solutions at and below 25^°C.Polymer Chemistry,2016, 7, 176 – 183.

25. Qiuping Yu, Yi Ding, Hui Cao, Xinhua Lu,Yuanli Cai*.Use of polyion complexation for polymerization-induced self-assembly in water under visible light irradiation at 25^°C.ACS Macro Letters,2015, 4, 1293 − 1296.

26. Na Xu, Jie Han, Zhengguang Zhu, Bo Song, Xinhua Lu,Yuanli Cai*.Directional supracolloidal self-assembly via dynamic covalent bonds and metal coordination.Soft Matter,2015, 11, 5546 − 5553.

27. Lei Guo, Yi Ding, Jie Han, Na Xu, Xinhua Lu,Yuanli Cai*.Reconstruction of block copolymer micelles to long-range ordered dense nanopatterns via light-tunable hydrogen-bonding association.Macromolecular Rapid Communications,2015, 36, 1505 − 1510.

28. Zhengguang Zhu, Na Xu, Qiuping Yu, Lei Guo, Hui Cao, Xinhua Lu,Yuanli Cai*.Construction and self-assembly of single-chain polymer nanoparticles via coordination association and electrostatic repulsion in water.Macromolecular Rapid Communications,2015, 36, 1521 − 1527.

29. Yanyan Jiang, Na Xu, Jie Han, Qiuping Yu, Pan Gao, Xinhua Lu,Yuanli Cai*.Direct synthesis of interface-decorated reactive block copolymer nanoparticles via polymerisation-induced self-assembly.Polymer Chemistry,2015, 6, 4955 − 4965.

30. Hui Shi, Kaiyi Zhou, Qiuping Yu, Zhigang Cui, Yanyan Jiang, Xinhua Lu andYuanli Cai*.Programmable self-assembly of cystamine-block copolymer in response to pH and progressive reduction-ionization-oxidation.Polymer Chemistry,2015, 6, 7455 − 7463.

31. Guangxiang Li, Na Xu, Qiuping Yu, Xinhua Lu, Hong Chen,Yuanli Cai*.Acceleration and selective monomer addition during aqueous RAFT copolymerization of ionic monomers at 25 °C.Macromolecular Rapid Communications,2014, 35, 1430 − 1435.

32. Xianghua Tang, Jie Han, Zhengguang Zhu, Xinhua Lu, Hong Chen,Yuanli Cai*.Facile synthesis, sequence-tuned thermoresponsive behaviours and reaction-induced reorganization of water-soluble keto-polymers.Polymer Chemistry,2014, 5, 4115 − 4123.

33. Xuewen Wu, Na Xu, Zhengguang Zhu,Yuanli Cai*, Ying Zhao*, Dujin Wang. Subcomponent self-assembly of polymer chains based on dynamic and geometrical coordination diversity of the first row transition metal ions.Polymer Chemistry,2014, 5, 1202 − 1209.

34. Fen Wu, Xianghua Tang, Lei Guo, Ke Yang,Yuanli Cai*.Switching preorganization and thermoresponsive behavior of a water-soluble polymer via light-tunable hydrogen bonding.Soft Matter,2013, 9, 4036 − 4044.

35. Xuejun Chen, Na Xu, Nan Li, Lican Lu,Yuanli Cai*, Ying Zhao*, Dujin Wang. Programmable selectivity of metal-imine bond coordination in subcomponent self-assembly of a primary amine based block copolymer.Soft Matter,2013, 9, 1885 − 1894.

36. Jianyu Tong, Yi Shi, Guhuan Liu, Tao Huang, Na Xu, Zhengguang Zhu,Yuanli Cai*.Visible light mediated fast iterative RAFT synthesis of amino-based reactive copolymers in water at 20^°C.Macromolecular Rapid Communications,2013, 34, 1827 − 1832.

37. Junjie Deng,Yuanli Cai*.Botryoid-shaped reactive nanoparticles through spontaneous structural reorganization of terpolymer micelles.Macromolecular Rapid Communications,2013, 34, 1459 − 1463.

38. Zhenhua Hao, Guangxiang Li, Ke Yang,Yuanli Cai*.Thermoresponsive synergistic hydrogen bonding switched by several guest units in a water-soluble polymer.Macromolecular Rapid Communications,2013, 34, 411 − 1463.

39. Guhuan Liu, Hui Shi, Yuru Cui, Jianyu Tong, Ying Zhao, Dujin Wang,Yuanli Cai*.Toward rapid aqueous RAFT polymerization of primary amine functional monomer under visible light irradiation at 25^°C.Polymer Chemistry,2013, 4, 1176 − 1182.

40. Ying Chen, Fuxin Liang*, Haili Yang, Chengliang Zhang, Qian Wang, Xiaozhong Qu, Jiaoli Li,Yuanli Cai*, Dong Qiu, and Zhenzhong Yang*. Janus nanosheets of polymer-inorganic layered composites.Macromolecules,2012, 45, 1460 − 1467.

41. Jian Yang, Yuhai Liu, Tao Wen, Xiaoxiao Wei, Zhiyong Li,Yuanli Cai*, Yunlan Su*, Dujin Wang. Controlled mineralization of calcium carbonate on the surface of nonpolar organic fibers.Crystal Growth Design,2012, 12, 29 − 32.

42. Yufang Tang, Zhilin Liu, Xuewen Wu, Guhuan Liu, Ke Yang, Yaohua Li, Lican Lu,Yuanli Cai*.Modulating structural stability and acid sensitivity of photosensitive polymer micelles simply via one-batch UV irradiation.Journal of Polymer Science Part A: Polymer Chemistry,2012, 50, 2878 − 2888.

43. Zhilin Liu, Yufang Tang, Nan Li, Lican Lu, Junjie Deng,Yuanli Cai*.Modulating light-tunable acid sensitivity of a bioinspired polymer simply by adjusting the position of a single methoxy substituent.Journal of Polymer Science Part A: Polymer Chemistry,2012, 50, 495 − 508.

44. Ke Yang, Xiangqian Wei, Fen Wu, Chaowei Cao, Junjie Deng,Yuanli Cai*.Sequence control over thermo-triggered micellization and smart nanogels of copolymers based on PEGMA and aldehyde-functionalized monomer.Soft Matter,2011, 7, 5861 − 5872.

45. Chaowei Cao, Ke Yang, Fen Wu, Xiangqian Wei, Lican Lu,Yuanli Cai*.Thermally Induced Swellability and Acid-Liable Dynamic properties of microgels of copolymers based on PEGMA and aldehyde-functionalized monomer,Macromolecules,2010, 43, 9511 − 521.

46. Huan Gao, Guhuan Liu, Xuejun Chen, Zhenhua Hao, Jianyu Tong, Lican Lu,Yuanli Cai*, Feng Long, Mingqiang Zhu. Media-modulated interchain or intrachain coordination of amphiphilic block copolymer micelles.Macromolecules,2010, 43, 6156 − 6165.

47. Jun Sun, Yifeng Peng, Ying Chen, Yu Liu, Junjie Deng, Lican Lu,Yuanli Cai*.Effect of molecular structure on thermo-responsive behaviors of pyrrolidone-based water-soluble polymers.Macromolecules,2010, 43, 4041 − 4049.

48. Junjie Wu, Songmiao Liang, Hongjun Dai, Xiaoyan Zhang, Xiaolan Yu,Yuanli Cai*, Lina Zhang, Ning Wen, Bin Jiang, Jian Xu*. Structure and properties of cellulose/chitin blended hydrogel membranes fabricated via a solution pre-gelation technique.Carbohydrate Polymers,2010, 79, 677 − 684.

49. Yi Shi, Guhuan Liu, Huan Gao, Lican Lu,Yuanli Cai*.Effect of mild visible light on rapid aqueous RAFT polymerization of water-soluble acrylic monomers at ambient temperature: initiation and activation.Macromolecules,2009, 42, 3917 − 3926.

50. Yi Shi, Huan Gao, Lican Lu,Yuanli Cai*.Ultra-fast RAFT polymerisation of poly(ethylene glycol) acrylate in aqueous media under mild visible light radiation at 25^°C.Chemical Communications,2009, 1368 − 1370.

51. Qing Luo, Haimei Zheng, Ye Peng, Gao Huan, Lican Lu,Yuanli Cai*.Facile synthesis of well-defined pH-liable Schiff-base-type photosensitive polymers via visible-light-activated ambient temperature RAFT polymerization.Journal of Polymer Science Part A: Polymer Chemistry,2009, 47, 6668 − 6681.

52. Shanshan Jia, Junjie Fei*, Junjie Deng,Yuanli Cai*, Junan Li. Direct electrochemistry and electrocatalysis of hemoglobin immobilized in an amphiphilic diblock copolymer film.Sensors and Actuators B: Chemical,2009, 138, 244 − 250.

53. Yaohua Li, Yufang Tang, Ke Yang, Xiaoping Chen, Lican Lu,Yuanli Cai*.Facile synthesis and photo-tunable properties of photosensitive polymer whose chromophores bound with pH-labile cyclic acetal linkages.Macromolecules,2008, 41, 4597 − 4606.

54. Junjie Deng, Yi Shi, Wending Jiang, Yifeng Peng, Lican Lu,Yuanli Cai*.Facile synthesis and thermoresponsive behaviors of a well-defined pyrrolidone based hydrophilic polymer.Macromolecules,2008, 41, 3007 − 3014.

55. Haijia Zhang, Junjie Deng, Lican Lu,Yuanli Cai*.Ambient temperature RAFT polymerization of styrene and its functional derivatives under mild long-wave UV-visible radiation.Macromolecules,2007, 40, 9252 − 9261.

56. Huiwen Yin, Haimei Zheng, Lican Lu, Pengsheng Liu,Yuanli Cai*.Highly efficient and well controlled ambient temperature RAFT polymerization of glycidyl methacrylate under visible light radiation.Journal of Polymer Science Part A: Polymer Chemistry,2007, 45, 5091 − 5102.

57. Ping Jiang, Yi Shi, Pengsheng Liu,Yuanli Cai*.Synthesis of well-defined glycidyl methacrylate based block copolymers with self-activation and self-initiation behaviors via ambient temperature atom transfer radical polymerization.Journal of Polymer Science Part A: Polymer Chemistry,2007, 45, 2947 − 2958.

58. Wending Jiang, Lican Lu,Yuanli Cai*.Highly efficient and well-controlled ambient temperature RAFT polymerization under solar radiation.Macromolecular Rapid Communications,2007, 28, 725 − 728.

59. Lican Lu, Haijia Zhang, Nianfa Yang,Yuanli Cai*.Toward rapid and well-controlled ambient temperature RAFT polymerization under UV-vis radiation: effect of radiation wave range.Macromolecules,2006, 39, 3770 − 3776.

60. Shaojun Chen, Qi Cao, Bo Jing,Yuanli Cai*.Pengsheng Liu, Jinglian Hu, Effect of microphase-separation promoters on the shape-memory behavior of polyurethane.Journal of Applied Polymer Science,2006, 102, 5224 − 5231.

61. Hongmei Kang,Yuanli Cai*, Junjie Deng, Haijia Zhang，Yufang Tang, Pengsheng Liu. Synthesis and aqueous solution behavior of phosphonate-functionalized chitosans.European Polymer Journal,2006, 42, 2678 − 2685.

62. Lican Lu, Nianfa Yang*,Yuanli Cai*.Well-controlled reversible addition fragmentation chain transfer radical polymerization under ultraviolet radiation at ambient temperature.Chemical Communications,2005, 5287 − 5288.

63. Syuji Fujii,Yuanli Cai, Jonathan V. M. Weaver, Steven P. Armes*. Synthesis of shell cross-linked micelles using new acidic ABC triblock copolymers and their application as pH-responsive particulate emulsifiers.Journal of the American Chemical Society,2005, 127, 7304 − 7305.

64. Yuanli Cai, Steven P. Armes*. Synthesis of well-defined, Y-shaped zwitterionic block copolymers via atom transfer radical polymerization.Macromolecules,2005, 38, 271 − 279.

65. Yuanli Cai, Yiqing Tang, Steven P. Armes*. Direct synthesis and stimulus-responsive micellization of Y-shaped hydrophilic block copolymers.Macromolecules,2004, 37, 9728 − 9737.

66. Yuanli Cai, Steven P. Armes*. A zwitterionic ABC triblock copolymer that forms a ‘trinity’ of micellar aggregates in aqueous solution.Macromolecules,2004, 37, 7116 − 7122.

67. Yuanli Cai, Carine Burguiere, Steven P. Armes*. Direct synthesis and aqueous solution properties of Y-shaped, stimulus-responsive block copolymer surfactants.Chemical Communications,2004, 802 − 803.

68. Yuanli Cai, Markus Hartenstein, Axel H. E. Müller*. Synthesis of amphiphilic graft copolymers ofn-butyl acrylate and acrylic acid by atom transfer radical copolymerization of macromonomers.Macromolecules,2004, 37, 7484 − 7490.

69. Yuanli Cai, Dujin Wang*, Yizhuang Xu, Xianbo Hu, Ying Zhao, Jinguang Wu, Duanfu Xu. Self-assembled mesomorphic structure of complexes of branched polyethyleneimine with octadecanoic acid.Macromolecular Rapid Communications,2001, 22, 504 − 507.

70. Yuanli Cai, Dujin Wang*, Xianbo Hu, Yizhuang Xu, Ying Zhao, Jinguang Wu, Duanfu Xu. Crystalline polymorphism of alkyl chains in supramolecular complexes of polyethyleneimine with octadecanic acid.Macromolecular Chemistry and Physics, 2001, 202, 2434 − 2439.

71. Yuanli Cai*, Pengsheng Liu, Xianbo Hu, Dujin Wang, Duanfu Xu. Microstructure-tensile properties relationships of polyurethane/poly(urethane modified bismaleimide-bismaleimide) interpenetrating polymer networks.Polymer, 2000, 41, 5653 − 5660.

72. Yuanli Cai*, Pengsheng Liu. Synthesis and characterization of polyurethane/poly(urethane modified bismaleimide-bismaleimide) IPNs.Chinese Chemical Letters, 2000, 11, 525 − 526.

73. Yuanli Cai*, Zhongming Jiang, Dafong Yang, Pengsheng Liu. Structure and thermal properties of PU/P(BMI-UBMI) IPNs.Journal of Applied Polymer Science, 1998, 68, 1689 − 1694.

（更新日期：2024年3月28日）